Hydrocarbons

An optically active alkyl bromide C4H9Br, reacts with ethanolic KOH to form major compound [A] which reacts with bromine to give compound [B]. Compound [B] reacts with ethanolic KOH and sodamide to give compound [C]. One molecule of water adds to compound [C] on warming with mercuric sulphate and dilute sulphuric acid at 333 K to form compound [D]. The functional group in compound D will be confirmed by :

1. Haloform test
2. Lucas test
3. Silver mirror test
4. Benedict test

[figure] Compound (X) is subjected to the sequence of reactions as shown above. Molar mass of the major product (Y) formed is g mol-1. (Given molar mass in g mol-1 C : 12, H : 1, O : 16 )

1. 90
2. 118
3. 160
4. 125

Given below are two statements for the following reaction sequence. [figure] In the light of the above statements, choose the correct answer from the options given below :

1. Statement I is true but Statement II is false
2. Both Statement I and Statement II are true
3. Statement I is false but Statement II is true
4. Both Statement I and Statement II are false

But-2-yne and hydrogen (one mole each) are separately treated with (i) Pd/C and (ii) Na/ liq. NH3 to give the products X and Y respectively. [figure] Identify the incorrect statements. Choose the correct answer from the options given below :

1. B and D Only
2. A and C Only
3. A and B Only
4. B and C Only

[figure] 'P' is

1. [figure]
2. [figure]
3. [figure]
4. [figure]

Identify the structure of the final product (D) in the following sequence of the reactions : [figure] Total number of sp2 hybridised carbon atoms in product D is .

An optically active alkyl halide C4H9Br [A] reacts with hot KOH dissolved in ethanol and forms alkene [B] as major product which reacts with bromine to give dibromide [C]. The compound [C] is converted into a gas [D] upon reacting with alcoholic NaNH2. During hydration 18 gram of water is added to 1 mole of gas [D] on warming with mercuric sulphate and dilute acid at 333 K to form compound [E]. The IUPAC name of compound [E] is :

1. Butan-2-ol
2. But-2-yne
3. Butan-2-one
4. Butan-1-al

Identify product [A], [B] and [C] in the following reaction sequence. CH3-C CH [H2]Pd/C [A] [(ii) Zn, H2O](i) O3 [B] + [C]

1. [A]: CH3-CH=CH2, [B]: CH3CHO, [C]: CH3CH2OH
2. [A]: CH3-CH=CH2, [B]: CH3CHO, [C]: HCHO
3. [A]: CH3CH2CH3, [B]: CH3CHO, [C]: HCHO
4. [A]: CH2=CH2, [B]: H3C- O \|C-CH3, [C]: HCHO