Ques. 1JEE Main 2025, 23 January (Evening Shift)
Consider the following reactions K2Cr2O7 [-H2O]KOH [A] [-H2O]H2SO4 [B] + K2SO4 The products [A] and [B], respectively are :
- K2Cr(OH)6 and Cr2O3
- K2CrO4 and Cr2O3
- K2CrO4 and K2Cr2O7
- K2CrO4 and CrO
Answer
(3) K2CrO4 and K2Cr2O7
Solution
CrO42- and Cr2O72- interconvert with pH; Cr stays +6:
[figure]
∴ [A] = K2CrO4, [B] = K2Cr2O7
Answer: (3)