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Chemical Kinetics · Question 41

JEE Main 2025 (Online) 29th January Morning ShiftMCQEasy📈 Topic in 10% papers+4−1
1

The reaction A2 + B2 2AB follows the mechanism: A2 k-1 k1 A + A (fast) A + B2 k2 AB + B (slow) A + B AB (fast) The overall order of the reaction is:

  1. 3
  2. 2.5
  3. 1.5
  4. 2

Answer

(3) 1.5

Solution

Rate is decided by the slow step: r = k2[A][B2]

A is an intermediate; from the fast equilibrium: K = k1k-1 = [A]2[A2]

[A] = K1/2[A2]1/2

r = k2K1/2[A2]1/2[B2]

Overall order = 12 + 1 = 1.5

Answer: (3)

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2

array|c|c| [A]0/ mol L-1 & t1/2/min \ 0.100 & 200 \ 0.025 & 100 \ array For a given reaction R P, t1/2 is related to [A]0 as given in table. Given: 2 = 0.30 Which of the following is true? Choose the correct answer from the options given below:

  1. A and C Only
  2. A, B and D Only
  3. A and B Only
  4. C and D Only
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3

Consider an elementary reaction A(g) + B(g) C(g) + D(g) If the volume of reaction mixture is suddenly reduced to 13 of its initial volume, the reaction rate will become 'x' times of the original reaction rate. The value of x is :

  1. 3
  2. 9
  3. 13
  4. 19
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4

For bacterial growth in a cell culture, growth law is very similar to the law of radioactive decay. Which of the following graphs is most suitable to represent bacterial colony growth? Where N - Number of bacteria at any time, N0 - Initial number of bacteria.

  1. [figure]
  2. [figure]
  3. [figure]
  4. [figure]
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