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Organic Chemistry – Some Basic Principles and Techniques · Question 66

AIPMT 2002MCQEasy📈 Topic in 12% papers+4−1
1

IUPAC name of the following is CH2=CH-CH2-CH2-C CH

  1. 1-hexyne-5-ene
  2. 1,5-hexenyne
  3. 1-hexene-5-yne
  4. 1,5-hexynene

Answer

(3) 1-hexene-5-yne

Solution

The parent chain has 6 carbon atoms with one C=C and one C C ⇒ hexenyne.

Numbering from either end gives the multiple bonds the locants 1, 5.

∵ As per NCERT (IUPAC rules), when there is a tie, the double bond gets the lower number.

⇒ Numbering starts from the CH2= end: 1CH2= 2CH- 3CH2- 4CH2- 5C 6CH

∴ Name: hex-1-en-5-yne (written in the older style as 1-hexene-5-yne).

Answer: (3)

AIPMT 2002

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2

CH2- O \|C-CH3 and CH2= O |C-CH3 are

  1. resonating structures
  2. tautomers
  3. geometrical isomers
  4. optical isomers
AIPMT 2002
3

The incorrect IUPAC name is

  1. CH3- O \|C- CH3 |CH-CH3 2-methyl-3-butanone
  2. CH3- CH3 |CH- CH2CH3 |CH-CH3 2,3-dimethylpentane
  3. CH3-C CCH(CH3)2 4-methyl-2-pentyne
  4. CH3 Cl |CH Br |CHCH3 2-bromo-3-chlorobutane
AIPMT 2001
4

The correct acidic order of the following is [figure]

  1. I > II > III
  2. III > I > II
  3. II > III > I
  4. I > III > II
AIPMT 2001
5

Which is maximum stable?

  1. 1-Butene
  2. cis-2-Butene
  3. trans-2-Butene
  4. All have same stability.
AIPMT 2000
6

Polarisation in acrolein can be described as

  1. + CH2=CH- + CHO
  2. - CH2=CH- + CHO
  3. - CH2=CH-CH + O
  4. + CH2=CH-CH - O
AIPMT 2000

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