Consider a hydrogen atom with vk, rk, and Kk denoting the velocity, orbital radius and kinetic energy of the electron in the kth orbit, respectively. The electron undergoes a transition from the nth orbit, emitting radiation corresponding to the Lyman series. Considering h to be the Planck's constant and 0 the permittivity of the free space, the correct statement(s) is/are:
- Magnitude of change in kinetic energy of electron can be expressed as h4 | nvnrn - v1r1 |.
- Magnitude of change in de Broglie wavelength of the electron can be expressed as e24 0 | 1Kn - 1K1 |.
- Frequency of the radiation emitted can be expressed as e28 0 h ( 1r1 - 1rn ).
- Magnitude of change in total energy of the electron can be expressed as h2 | v1r1 - nvnrn |.
Answer
(1) Magnitude of change in kinetic energy of electron can be expressed as h4 | nvnrn - v1r1 |., (3) Frequency of the radiation emitted can be expressed as e28 0 h ( 1r1 - 1rn ).
Solution
Lyman series: transition n 1. Bohr: mvk rk = kh2 , Kk = e28 0 rk, Ek = -Kk.
(A) Kk = 12mvk2 = 12 kh2 vk rkvk2 = h4 kvkrk, so | K| = h4 | nvnrn - v1r1 | — correct.
(B) k = 2 rkk with rk = e28 0 Kk gives k = e24 0 kKk; | | = e24 0 | 1nKn - 1K1 | — the factor n is missing, incorrect.
(C) h = En - E1 = e28 0 ( 1r1 - 1rn ) — correct.
(D) | E| = | K| = h4 | |, not h2 | | — incorrect.
Answer: (A), (C)