Aldehydes, Ketones and Carboxylic Acids · Question 1

'x' is the product which is obtained from benzene by reacting it with carbon monoxide and hydrogen chloride in the presence of cuprous chloride. 'y' is the major product obtained from the benzene by reacting it with ethanoyl chloride in the presence of anhydrous AlCl3. Product (major) obtained by heating x and y in the presence of alkali is z. Total number of π (pi) electrons in z is .

'x' is the product which is obtained by the hydrolysis of prop-1-yne in the presence of mercuric sulphate under dilute acidic medium at 333 K. 'y' is the product which is obtained by the reaction of ethane nitrile with methyl magnesium bromide in dry ether followed by hydrolysis. IUPAC name of product obtained from 'x' and 'y' in the presence of barium hydroxide followed by heating is :

1. 2-Methylpent-4-en-3-one
2. 4-Methylpent-3-en-2-one
3. 4-Methylpent-1-ene
4. 2-Methylpent-3-one

" P " is a hydrocarbon of molecular formula:- C8H14. On ozonolysis, " P " forms "Q". "Q" on treatment with alkali under reflux condition produces "R", which on treatment with I2/NaOH gives a yellow precipitate. Acidification of the solution gives "S". The structure of "S" is given below:- [figure] The correct structure of P is

1. [figure]
2. [figure]
3. [figure]
4. [figure]

Complete the following reaction sequence and give the name of major product 'P'. [figure]

1. 2-Chloropropanoic acid
2. 3-Chloropropanoic acid
3. 1-Chloropropane
4. 2-Chloropropane

Given below are two statements: In the light of the above statements, choose the correct answer from the options given below:

1. Both Statement I and Statement II are true
2. Both Statement I and Statement II are false
3. Statement I is true but Statement II is false
4. Statement I is false but Statement II is true

Consider the following sequence of reactions to give the major product (X) [figure] P g of the major product (X) formed is reacted with NaHCO3 solution to liberate a gas which occupied 11.2 dm3 at STP. P = g. (Given molar mass in g mol-1 H : 1, C : 12, O : 16, Cl : 35.5)

An organic compound “x” where molar ratio of C, O and H are equal, on treatment with 50% KOH under reflux followed by acidification produced “y”. The most likely structure of “y” is: [Molar mass of ‘x’ is 58 g mol-1]

1. [figure]
2. CH3-CH=CH-CH=O
3. [figure]
4. [figure]

A molecule (X) with following structure under mild acidic condition is hydrolysed to produce (Y) and (Z). Identify the correct statements about (Y) and (Z). [figure] Choose the correct answer from the options given below :

1. A, B and C Only
2. B and C Only
3. C and D Only
4. A and D Only

Given below are the four isomeric compounds (P, Q, R, S) [figure] Identify correct statements from below. Choose the correct option.

1. C and E only
2. A and E only
3. A, B, D and E only
4. A, C and E only

The correct order of acidic strength of the major products formed in the given reactions, is : Choose the correct answer from the options given below :

1. C > A > D > B
2. A > D > C > B
3. A > D > B > C
4. C > B > A > D