During the melting of a slab of ice at 273 K at atmospheric pressure :
- Internal energy of ice-water system remains unchanged.
- Positive work is done by the ice-water system on the atmosphere.
- Positive work is done on the ice-water system by the atmosphere.
- Internal energy of the ice-water system decreases.
Answer
(3) Positive work is done on the ice-water system by the atmosphere.
Solution
Ice is less dense than water, so on melting the volume of the system decreases: V < 0.
Work done by the system: W = P V < 0
positive work is done on the ice-water system by the atmosphere.
Latent heat is absorbed: Q = mL > 0
U = Q - W = mL - P V > 0 internal energy increases, so (1) and (4) are wrong.
Answer: (3)