First ionisation enthalpy values of first four group 15 elements are given below. Choose the correct value for the element that is a main component of apatite family :
- 834 kJ mol-1
- 947 kJ mol-1
- 1402 kJ mol-1
- 1012 kJ mol-1
Answer
(4) 1012 kJ mol-1
Solution
Apatite Ca5(PO4)3X ⇒ phosphorus.
IE1 falls down group 15: N 1402 > P 1012 > As 947 > Sb 834 kJ mol-1.
Answer: (4)