Which of the following statements are correct about Zn, Cd and Hg? Choose the most appropriate from the options given below:
- C, D only
- B, C only
- A, D only
- B, D only
Answer
(4) B, D only
Solution
Zn, Cd, Hg: (n-1)d10ns2 — no unpaired d electrons.
A: no unpaired d electrons ⇒ weak metallic bonding ⇒ LOWEST enthalpy of atomisation in their series ⇒ A is false
B: Zn, Cd show only +2; Hg shows +1 ( Hg22+) and +2 ⇒ B is true
C: M2+ is d10 ⇒ diamagnetic ⇒ C is false
D: weak metallic bonding ⇒ soft, low-melting (Hg is a liquid) ⇒ D is true
∴ B, D only
Answer: (4)