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Haloalkanes and Haloarenes

JEE Main 2024 (Online) 31st January Morning ShiftMCQEasy📈 Topic in 15% papers+4−1
Ques. 1JEE Main 2024, 31 January (Morning Shift)

The product (C) in the below mentioned reaction is : CH3-CH2-CH2-Br [ ]KOH(alc) A HBr B [KOH(aq)] C

  1. Propan-1-ol
  2. Propyne
  3. Propan-2-ol
  4. Propene

Answer

(3) Propan-2-ol

Solution

CH3-CH2-CH2-Br [ ]KOH(alc) (A)CH3-CH=CH2

∵ alc. KOH ⇒ dehydrohalogenation (β-elimination)

CH3-CH=CH2 HBr (B)CH3- Br |CH-CH3

∵ Markovnikov addition: H+ adds to =CH2 ⇒ more stable 2° carbocation

CH3- Br |CH-CH3 [KOH(aq)] (C)CH3- OH |CH-CH3

∵ aq. KOH ⇒ substitution of Br by OH ⇒ C = propan-2-ol

Answer: (3)

Keep practising — Haloalkanes and Haloarenes

Ques. 2JEE Main 2024, 31 January (Morning Shift)

[figure] The total number of hydrogen atoms in product A and product B is .

Ques. 3JEE Main 2024, 31 January (Evening Shift)

Identify structure of 2,3-dibromo-1-phenylpentane.

  1. [figure]
  2. [figure]
  3. [figure]
  4. [figure]
Ques. 4JEE Main 2024, 31 January (Evening Shift)

Identify A and B in the following reaction sequence. [figure]

  1. [figure]
  2. [figure]
  3. [figure]
  4. [figure]
Ques. 5JEE Main 2024, 30 January (Morning Shift)

Example of vinylic halide is :

  1. [figure]
  2. [figure]
  3. [figure]
  4. [figure]
Ques. 6JEE Main 2024, 30 January (Morning Shift)

Given below are two statements : one is labelled as Assertion (A) and the other is labelled as Reason (R). In the light of the above statements, choose the most appropriate answer from the options given below :

  1. (A) is true but (R) is false
  2. (A) is false but (R) is true
  3. Both (A) and (R) are true but (R) is not the correct explanation of (A)
  4. Both (A) and (R) are true and (R) is the correct explanation of (A)
Ques. 7JEE Main 2024, 30 January (Evening Shift)

Given below are two statements: In the light of the above statements, choose the most appropriate from the options given below:

  1. Both Statement I and Statement II are true.
  2. Statement I is true but Statement II is false.
  3. Both Statement I and Statement II are false.
  4. Statement I is false but Statement II is true.
Ques. 8JEE Main 2024, 29 January (Morning Shift)

Given below are two statements : one is labelled as Assertion A and the other is labelled as Reason R : In the light of the above statements, choose the most appropriate from the options given below :

  1. A is true but R is false
  2. Both A and R are true but R is NOT the correct explanation of A
  3. A is false but R is true
  4. Both A and R are true and R is the correct explanation of A
Ques. 9JEE Main 2024, 29 January (Evening Shift)

Alkyl halide is converted into alkyl isocyanide by reaction with

  1. KCN
  2. NH4CN
  3. NaCN
  4. AgCN
Ques. 10JEE Main 2024, 27 January (Morning Shift)

The correct statement regarding nucleophilic substitution reaction in a chiral alkyl halide is ;

  1. Retention occurs in SN1 reaction and inversion occurs in SN2 reaction.
  2. Racemisation occurs in SN1 reaction and retention occurs in SN2 reaction.
  3. Racemisation occurs in both SN1 and SN2 reactions.
  4. Racemisation occurs in SN1 reaction and inversion occurs in SN2 reaction.
Ques. 11JEE Main 2024, 27 January (Evening Shift)

Which among the following halide/s will not show SN1 reaction: Choose the most appropriate answer from the options given below :

  1. (B) and (C) only
  2. (A), (B) and (D) only
  3. (B) only
  4. (A) and (B) only

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