Which of the following statements are correct? Choose the correct answer from the options given below:
- A, C and D Only
- B and C Only
- B and D Only
- B, C and E Only
Answer
(2) B and C Only
Solution
A. Incorrect. Adding an electron is not always exothermic: for noble gases (and for atoms such as Be and N) energy has to be supplied, i.e. egH is positive.
B. Correct. Energy is always required to remove an electron from an isolated gaseous atom, so ionisation is always endothermic.
C. Correct. B (2s2 2p1): the 2p electron is shielded by the 2s electrons and is removed more easily than a 2s electron of Be (2s2).
i H1: B (801 kJ mol-1) < Be (899 kJ mol-1)
D. Incorrect. As per NCERT, the electronegativity of an element is not constant; it varies with the atom to which it is bonded. C bonded to four Cl atoms in CCl4 is more electronegative than C in CH4.
E. Incorrect. Electropositive character increases down group 1; Li is the least electropositive alkali metal (Cs is the most electropositive among the stable ones).
Correct statements: B and C only
Answer: (2)