Given below are two statements : In the light of the above statements, choose the correct answer from the options given below :
- Both Statement I and Statement II are true
- Both Statement I and Statement II are false
- Statement I is true but Statement II is false
- Statement I is false but Statement II is true
Answer
(4) Statement I is false but Statement II is true
Solution
Statement I: across a period, nuclear charge increases and atomic size decreases, so first ionisation enthalpy generally increases.
i H1 (kJ mol-1): Na 496 < Mg 737 < Cl 1256 < Ar 1520
⇒ the order is Na < Mg < Cl < Ar, not Na > Mg > Cl > Ar ∴ Statement I is false.
Statement II: Ca = [Ar]4s2; after losing two electrons, Ca2+ has the stable noble-gas configuration [Ar].
The third electron must come from the inner 3p orbital ⇒ third ionisation enthalpy of Ca is very high.
Al ([Ne]3s23p1), B (1s22s22p1) and Fe ([Ar]3d64s2) lose their third electron from the valence shell.
∴ Statement II is true.
Answer: (4)