1
The oxidation states of sulphur in the anions SO32-, S2O42- and S2O62- follow the order
- S2O42- < SO32- < S2O62-
- SO32- < S2O42- < S2O62-
- S2O42- < S2O62- < SO32-
- S2O62- < S2O42- < SO32-
Answer
(1) S2O42- < SO32- < S2O62-
Solution
Let the oxidation number of S be x (O = −2).
SO32-: x + 3(-2) = -2 x = +4
S2O42-: 2x + 4(-2) = -2 x = +3
S2O62-: 2x + 6(-2) = -2 x = +5
S2O42- (+3) < SO32- (+4) < S2O62- (+5)
Answer: (1)
AIPMT 2003