Amines

In the following reaction sequence, P, Q, S and T are the major products. [figure] The correct statement(s) about P, Q, S and T is(are)

1. Q on treatment with ethanol generates an aromatic aldehyde.
2. S gives positive phthalein dye test.
3. P is a dinitro compound.
4. T is a coloured compound.

The major products obtained from the reactions in List-II are the reactants for the named reactions mentioned in List-I. Match each entry in List-I with the appropriate entry in List-II and choose the correct option.

1. P → 2; Q → 4; R → 1; S → 3
2. P → 2; Q → 3; R → 4; S → 1
3. P → 5; Q → 3; R → 4; S → 2
4. P → 5; Q → 4; R → 2; S → 1

For the reaction sequence given below, the correct statement(s) is(are) [figure]

1. Both X and Y are oxygen containing compounds.
2. Y on heating with CHCl3/KOH forms isocyanide.
3. Z reacts with Hinsberg’s reagent.
4. Z is an aromatic primary amine.