Solutions

20 g hemoglobin in a 1 L aqueous solution (A) at 300 K is separated from pure water by semi permeable membrane. At equilibrium the height of solution in a tube dipped in a solution (A) is found to be 80.0 mm higher than the tube dipped in water. The molar mass of hemoglobin is kg mol-1. (Nearest integer) (Given : g = 10 m s-2, R = 8.3 kPa dm3 K-1 mol-1, density of solution = 1000 kg m-3)

A non-volatile, non-electrolyte solid solute when dissolved in 40 g of a solvent, the vapour pressure of the solvent decreased from 760 mm Hg to 750 mm Hg. If the same solution boils at 320 K, then the number of moles of the solvent present in the solution is . (Nearest integer) [Given: boiling point of the pure solvent = 319.5 K, Kb of the solvent = 0.3 K kg mol-1]

Two liquids A and B form an ideal solution. At 320 K, the vapour pressure of the solution, containing 3 mol of A and 1 mol of B is 500 mm Hg. At the same temperature, if 1 mol of A is further added to this solution, vapour pressure of the solution increases by 20 mm Hg. Vapour pressure (in mm Hg) of B in pure state is . (Nearest integer)

The osmotic pressure of a living cell is 12 atm at 300 K. The strength of sodium chloride solution that is isotonic with the living cell at this temperature is g L-1. (Nearest integer) Given : R = 0.08 L atm K-1 mol-1 Assume complete dissociation of NaCl (Given: Molar mass of Na and Cl are 23 and 35.5 g mol-1 respectively.)

A substance 'X' (1.5 g) dissolved in 150 g of a solvent 'Y' (molar mass = 300 g mol-1) led to an elevation of the boiling point by 0.5 K. The relative lowering in the vapour pressure of the solvent 'Y' is 10-2. (nearest integer) [Given: Kb of the solvent = 5.0 K kg mol-1] Assume the solution to be dilute and no association or dissociation of X takes place in solution.

The percentage dissociation of a salt (MX3) solution at given temperature (van't Hoff factor i = 2) is % (Nearest integer)

Sea water, which can be considered as a 6 molar (6 M) solution of NaCl, has a density of 2 g mL-1. The concentration of dissolved oxygen (O2) in sea water is 5.8 ppm. Then the concentration of dissolved oxygen (O2) in sea water, in terms of molality, is x 10-4 m. x = . (Nearest integer) Given: Molar mass of NaCl is 58.5 g mol-1 Molar mass of O2 is 32 g mol-1

When 1 g each of compounds AB and AB2 are dissolved in 15 g of water separately, they increased the boiling point of water by 2.7 K and 1.5 K respectively. The atomic mass of A (in amu) is 10-1 (Nearest integer) (Given : Molal boiling point elevation constant is 0.5 K kg mol-1)

If A2B is 30% ionised in an aqueous solution, then the value of van't Hoff factor (i) is 10-1.