Solutions · Question 26

Liquid A and B form an ideal solution. The vapour pressures of pure liquids A and B are 350 and 750 mm Hg respectively at the same temperature. If xA and xB are the mole fraction of A and B in solution while yA and yB are the mole fraction of A and B in vapour phase, then,

1. (xA - yA) < (xB - yB)
2. xAxB = yAyB
3. xAxB < yAyB
4. xAxB > yAyB

Match List - I with List - II. Choose the correct answer from the options given below :

1. A-III, B-I, C-IV, D-II
2. A-III, B-IV, C-I, D-II
3. A-II, B-I, C-IV, D-III
4. A-II, B-IV, C-I, D-III

XY is the membrane/partition between two chambers 1 and 2 containing sugar solutions of concentration c1 and c2 (c1 > c2) mol L-1. For the reverse osmosis to take place identify the correct condition. (Here p1 and p2 are pressures applied on chamber 1 and 2.) [figure] Choose the correct answer from the options given below:

1. A and C Only
2. A and D Only
3. B and D Only
4. C Only

Given below are two statements: In the light of the above statements, choose the most appropriate answer from the options given below :

1. Statement I is correct but Statement II is incorrect
2. Both Statement I and Statement II are incorrect
3. Statement I is incorrect but Statement II is correct
4. Both Statement I and Statement II are correct

Sea water, which can be considered as a 6 molar (6 M) solution of NaCl, has a density of 2 g mL-1. The concentration of dissolved oxygen (O2) in sea water is 5.8 ppm. Then the concentration of dissolved oxygen (O2) in sea water, in terms of molality, is x 10-4 m. x = . (Nearest integer) Given: Molar mass of NaCl is 58.5 g mol-1 Molar mass of O2 is 32 g mol-1

2 moles each of ethylene glycol and glucose are dissolved in 500 g of water. The boiling point of the resulting solution is: (Given : Ebullioscopic constant of water = 0.52 K kg mol-1)

1. 377.3 K
2. 379.2 K
3. 375.3 K
4. 277.3 K

A solution is made by mixing one mole of volatile liquid A with 3 moles of volatile liquid B. The vapour pressure of pure A is 200 mm Hg and that of the solution is 500 mm Hg. The vapour pressure of pure B and the least volatile component of the solution, respectively, are:

1. 1400 mm Hg, A
2. 1400 mm Hg, B
3. 600 mm Hg, A
4. 600 mm Hg, B

Which of the following graph correctly represents the plots of KH at 1 bar for gases in water versus temperature?

1. [figure]
2. [figure]
3. [figure]
4. [figure]

When 1 g each of compounds AB and AB2 are dissolved in 15 g of water separately, they increased the boiling point of water by 2.7 K and 1.5 K respectively. The atomic mass of A (in amu) is 10-1 (Nearest integer) (Given : Molal boiling point elevation constant is 0.5 K kg mol-1)

1.24 g of AX2 (molar mass 124 g mol-1) is dissolved in 1 kg of water to form a solution with boiling point of 100.0156°C, while 25.4 g of AY2 (molar mass 250 g mol-1) in 2 kg of water constitutes a solution with a boiling point of 100.0260°C. Kb(H2O) = 0.52 kg mol-1 Which of the following is correct?

1. AX2 and AY2 (both) are completely unionised.
2. AX2 and AY2 (both) are fully ionised.
3. AX2 is completely unionised while AY2 is fully ionised.
4. AX2 is fully ionised while AY2 is completely unionised.