Which compound has planar structure?
- XeF4
- XeOF2
- XeO2F2
- XeO4
Answer
(1) XeF4
Solution
In XeF4, Xe has 4 bond pairs and 2 lone pairs ⇒ sp3d2 hybridisation.
The two lone pairs occupy the two axial (trans) positions, so the four F atoms and Xe lie in one plane.
∴ As per NCERT, XeF4 is square planar.
XeO2F2 (sp3d, 1 lone pair) is see-saw shaped and XeO4 (sp3) is tetrahedral.
Answer: (1)