Identify the incorrect statement.
- PEt3 and AsPh3 as ligands can form d - d bond with transition metals
- The N - N single bond is as strong as the P - P single bond
- Nitrogen has unique ability to form p - p multiple bonds with nitrogen, carbon and oxygen
- Nitrogen cannot form d - p bond as other heavier elements of its group
Answer
(2) The N - N single bond is as strong as the P - P single bond
Solution
(1) Correct: P and As have vacant d orbitals, so PEt3 and AsPh3 form d - d bonds with transition metals.
(2) Incorrect: the N - N single bond is weaker than the P - P single bond because of strong repulsion between the lone pairs of the two small N atoms (short bond length).
(3) Correct: small size and high electronegativity of N allow p - p multiple bonds with N, C and O.
(4) Correct: N has no d orbitals in its valence shell, so it cannot form d - p bonds as P and heavier elements can.
Answer: (2)