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p-Block Elements (Group 15–18) · Question 8

RE-NEET (UG) 2024MCQEasy📈 Topic in 50% papers+4−1
1

Identify the incorrect statement.

  1. PEt3 and AsPh3 as ligands can form d - d bond with transition metals
  2. The N - N single bond is as strong as the P - P single bond
  3. Nitrogen has unique ability to form p - p multiple bonds with nitrogen, carbon and oxygen
  4. Nitrogen cannot form d - p bond as other heavier elements of its group

Answer

(2) The N - N single bond is as strong as the P - P single bond

Solution

(1) Correct: P and As have vacant d orbitals, so PEt3 and AsPh3 form d - d bonds with transition metals.

(2) Incorrect: the N - N single bond is weaker than the P - P single bond because of strong repulsion between the lone pairs of the two small N atoms (short bond length).

(3) Correct: small size and high electronegativity of N allow p - p multiple bonds with N, C and O.

(4) Correct: N has no d orbitals in its valence shell, so it cannot form d - p bonds as P and heavier elements can.

Answer: (2)

RE-NEET (UG) 2024

Keep practising — p-Block Elements (Group 15–18)

2

Given below are two statements : one is labelled as Assertion A and the other is labelled as Reason R. In the light of the above statements, choose the correct answer from the options given below:

  1. Both A and R are true but R is NOT the correct explanation of A.
  2. A is true but R is false.
  3. A is false but R is true.
  4. Both A and R are true and R is the correct explanation of A.
NEET (UG) 2023
3

Match List-I with List-II: Choose the correct answer from the options given below:

  1. A-III, B-IV, C-I, D-II
  2. A-I, B-III, C-IV, D-II
  3. A-III, B-IV, C-II, D-I
  4. A-I, B-III, C-II, D-IV
NEET (UG) 2023
4

Given below are two statements : one is labelled as Assertion (A) and the other is labelled as Reason (R) In the light of the above statements, choose the most appropriate answer from the options given below:

  1. Both (A) and (R) are correct and (R) is the correct explanation of (A).
  2. Both (A) and (R) are correct but (R) is not the correct explanation of (A).
  3. (A) is correct but (R) is not correct.
  4. (A) is not correct but (R) is correct.
NEET (UG) 2022
5

Given below are two statements In the light of the above statements, choose the most appropriate answer from the options given below :

  1. Both Statement I and Statement II are correct
  2. Both Statement I and Statement II are incorrect
  3. Statement I is correct but Statement II is incorrect
  4. Statement I is incorrect but Statement II is correct
NEET (UG) 2022
6

Which of the following reactions is a part of the large scale industrial preparation of nitric acid?

  1. Cu(NO3)2 + 2NO2 + 2H2O [500 K, 9 bar]Pt 4HNO3 + Cu
  2. NaNO3 + H2SO4 [500 K, 9 bar]Pt NaHSO4 + HNO3
  3. 4NH3 + 5O2 (from air) [500 K, 9 bar]Pt 4NO + 6H2O
  4. 4HPO3 + 2N2O5 [500 K, 9 bar]Pt 4HNO3 + P4O10
NEET (UG) 2022 (Phase 2)
7

Fluorine is a stronger oxidising agent than chlorine because : Choose the most appropriate answer from the options given :

  1. B and C only
  2. A and B only
  3. A and C only
  4. A and D only
NEET (UG) 2022 (Phase 2)
8

In the light of the above statements, choose the correct answer from the options given below.

  1. Statement I is incorrect but Statement II is true.
  2. Both Statement I and Statement II are true.
  3. Both Statement I and Statement II are false.
  4. Statement I is correct but Statement II is false.
NEET (UG) 2021
9

Noble gases are named because of their inertness towards reactivity. Identify an incorrect statement about them.

  1. Noble gases have large positive values of electron gain enthalpy
  2. Noble gases are sparingly soluble in water
  3. Noble gases have very high melting and boiling points
  4. Noble gases have weak dispersion forces
NEET (UG) 2021
10

In which one of the following arrangements the given sequence is not strictly according to the properties indicated against it?

  1. CO2 < SiO2 < SnO2 < PbO2 : Increasing oxidizing order
  2. HF < HCl < HBr < HI : Increasing acidic strength
  3. H2O < H2S < H2Se < H2Te : Increasing pKa values
  4. NH3 < PH3 < AsH3 < SbH3 : Increasing acidic character
NEET (UG) 2021
11

Urea reacts with water to form A which will decompose to form B. B when passed through Cu2+(aq), deep blue colour solution C is formed. What is the formula of C from the following?

  1. [Cu(NH3)4]2+
  2. Cu(OH)2
  3. CuCO3 Cu(OH)2
  4. CuSO4
NEET (UG) 2020

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