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Organic Chemistry – Some Basic Principles and Techniques

JEE Main 2024 (Online) 9th April Morning ShiftMCQEasy📈 Topic in 8% papers+4−1
Ques. 1JEE Main 2024, 9 April (Morning Shift)

Correct order of basic strength of Pyrrole, Pyridine and Piperidine is : [figure]

  1. Pyridine > Piperidine > Pyrrole
  2. Pyrrole > Piperidine > Pyridine
  3. Pyrrole > Pyridine > Piperidine
  4. Piperidine > Pyridine > Pyrrole

Answer

(4) Piperidine > Pyridine > Pyrrole

Solution

Basic strength depends on how available the lone pair on N is.

Piperidine: sp3 N with a localised lone pair, so it is the strongest base.

Pyridine: sp2 N (more s-character holds the lone pair closer), but the lone pair is localised (not in the π sextet), so it is weaker.

Pyrrole: the lone pair is part of the aromatic sextet (delocalised) and is hardly available, so it is the weakest.

∴ Piperidine > Pyridine > Pyrrole

Answer: (4)

Keep practising — Organic Chemistry – Some Basic Principles and Techniques

Ques. 2JEE Main 2024, 9 April (Morning Shift)

How many compounds among the following compounds show inductive, mesomeric as well as hyperconjugation effects? [figure]

Ques. 3JEE Main 2024, 9 April (Evening Shift)

The correct stability order of the following resonance structures of CH3-CH=CH-CHO is [figure]

  1. II > III > I
  2. II > I > III
  3. III > II > I
  4. I > II > III
Ques. 4JEE Main 2024, 8 April (Morning Shift)

Which of the following are aromatic?

  1. B and D only
  2. A and C only
  3. C and D only
  4. A and B only
Ques. 5JEE Main 2024, 8 April (Morning Shift)

In the given compound, the number of 2° carbon atom/s is . [figure]

  1. Two
  2. Three
  3. Four
  4. One
Ques. 6JEE Main 2024, 8 April (Morning Shift)

Given below are two statements : In the light of the above statements, choose the most appropriate answer from the options given below:

  1. Both Statement I and Statement II are incorrect.
  2. Both Statement I and Statement II are correct.
  3. Statement I is correct but Statement II is incorrect.
  4. Statement I is incorrect but Statement II is correct.
Ques. 7JEE Main 2024, 8 April (Evening Shift)

The shape of carbocation is :

  1. tetrahedral
  2. diagonal pyramidal
  3. diagonal
  4. trigonal planar
Ques. 8JEE Main 2024, 8 April (Evening Shift)

IUPAC name of following hydrocarbon(X) is : CH3- CH3 |CH-CH2- (X)CH2- CH3 |CH- CH3 |CH-CH2-CH3

  1. 2,5,6-Trimethyloctane
  2. 2-Ethyl-2,6-diethylheptane
  3. 3,4,7-Trimethyloctane
  4. 2-Ethyl-3,6-dimethylheptane
Ques. 9JEE Main 2024, 8 April (Evening Shift)

Total number of aromatic compounds among the following compounds is . [figure]

Ques. 10JEE Main 2024, 6 April (Morning Shift)

Functional group present in sulphonic acids is :

  1. -SO2
  2. [figure]
  3. -SO3H
  4. -SO4H
Ques. 11JEE Main 2024, 6 April (Evening Shift)

[figure] The correct arrangement for decreasing order of electrophilic substitution for above compounds is :

  1. (III) > (IV) > (II) > (I)
  2. (III) > (I) > (II) > (IV)
  3. (II) > (IV) > (III) > (I)
  4. (IV) > (I) > (II) > (III)

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