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Organic Chemistry – Some Basic Principles and Techniques

JEE Main 2024 (Online) 8th April Morning ShiftMCQMedium📈 Topic in 14% papers+4−1
Ques. 1JEE Main 2024, 8 April (Morning Shift)

Which of the following are aromatic?

  1. B and D only
  2. A and C only
  3. C and D only
  4. A and B only

Answer

(1) B and D only

Solution

[figure]

A: two sp3 carbons (marked) break the cyclic conjugation, so A is non-aromatic

B: the benzene ring is planar with 6π electrons, so B (styrene) is aromatic

C: [10]annulene has 10π electrons, but its two inner H atoms clash and the ring is not planar, so C is non-aromatic

D: [14]annulene is cyclic and conjugated with 14 = (4n + 2) electrons (n = 3), so D is aromatic

Hence B and D only.

Answer: (1)

Keep practising — Organic Chemistry – Some Basic Principles and Techniques

Ques. 2JEE Main 2024, 8 April (Morning Shift)

In the given compound, the number of 2° carbon atom/s is . [figure]

  1. Two
  2. Three
  3. Four
  4. One
Ques. 3JEE Main 2024, 8 April (Morning Shift)

Given below are two statements : In the light of the above statements, choose the most appropriate answer from the options given below:

  1. Both Statement I and Statement II are incorrect.
  2. Both Statement I and Statement II are correct.
  3. Statement I is correct but Statement II is incorrect.
  4. Statement I is incorrect but Statement II is correct.
Ques. 4JEE Main 2024, 8 April (Evening Shift)

The shape of carbocation is :

  1. tetrahedral
  2. diagonal pyramidal
  3. diagonal
  4. trigonal planar
Ques. 5JEE Main 2024, 8 April (Evening Shift)

IUPAC name of following hydrocarbon(X) is : CH3- CH3 |CH-CH2- (X)CH2- CH3 |CH- CH3 |CH-CH2-CH3

  1. 2,5,6-Trimethyloctane
  2. 2-Ethyl-2,6-diethylheptane
  3. 3,4,7-Trimethyloctane
  4. 2-Ethyl-3,6-dimethylheptane
Ques. 6JEE Main 2024, 8 April (Evening Shift)

Total number of aromatic compounds among the following compounds is . [figure]

Ques. 7JEE Main 2024, 6 April (Morning Shift)

Functional group present in sulphonic acids is :

  1. -SO2
  2. [figure]
  3. -SO3H
  4. -SO4H
Ques. 8JEE Main 2024, 6 April (Evening Shift)

[figure] The correct arrangement for decreasing order of electrophilic substitution for above compounds is :

  1. (III) > (IV) > (II) > (I)
  2. (III) > (I) > (II) > (IV)
  3. (II) > (IV) > (III) > (I)
  4. (IV) > (I) > (II) > (III)
Ques. 9JEE Main 2024, 6 April (Evening Shift)

Number of carbocations from the following that are not stabilized by hyperconjugation is . [figure]

Ques. 10JEE Main 2024, 5 April (Morning Shift)

Number of and bonds present in ethylene molecule is respectively :

  1. 3 and 1
  2. 5 and 1
  3. 4 and 1
  4. 5 and 2
Ques. 11JEE Main 2024, 5 April (Evening Shift)

The correct nomenclature for the following compound is : [figure]

  1. 2-carboxy-4-hydroxyhept-7-enal
  2. 2-formyl-4-hydroxyhept-7-enoic acid
  3. 2-carboxy-4-hydroxyhept-6-enal
  4. 2-formyl-4-hydroxyhept-6-enoic acid

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