Structures of four disaccharides are given below. Among the given disaccharides, the non-reducing sugar is :
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Answer
(1) [figure]
Solution
A sugar is reducing when it has a free hemiacetal/hemiketal –OH (free anomeric carbon).
(1) Sucrose: C1 of α-D-glucose is linked to C2 of β-D-fructose, so both anomeric carbons are used in the glycosidic bond no free anomeric –OH non-reducing.
(2) Maltose (α-1,4 link), (3) cellobiose (β-1,4 link) and (4) lactose (β-D-galactose C1 to C4 of glucose): the C1 –OH of the second glucose unit is free reducing sugars.
Answer: (1)