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Redox Reactions · Question 21

AIPMT 2008MCQMedium📈 Topic in 12% papers+4−1
1

Number of moles of MnO4- required to oxidize one mole of ferrous oxalate completely in acidic medium will be

  1. 7.5 moles
  2. 0.2 moles
  3. 0.6 moles
  4. 0.4 moles

Answer

(3) 0.6 moles

Solution

Ferrous oxalate is FeC2O4; both ions are oxidised by MnO4- in acidic medium.

Fe2+ Fe3+ + e-

C2O42- 2CO2 + 2e-

Electrons lost by 1 mol FeC2O4 = 1 + 2 = 3 mol

MnO4- + 8H+ + 5e- Mn2+ + 4H2O

Each mole of MnO4- accepts 5 mol electrons.

Moles of MnO4- = 35 = 0.6 mol

Answer: (3)

AIPMT 2008

Keep practising — Redox Reactions

2

Which is the best description of the behaviour of bromine in the reaction given below? H2O + Br2 HOBr + HBr

  1. Proton acceptor only
  2. Both oxidised and reduced
  3. Oxidised only
  4. Reduced only
AIPMT 2004
3

The oxidation states of sulphur in the anions SO32-, S2O42- and S2O62- follow the order

  1. S2O42- < SO32- < S2O62-
  2. SO32- < S2O42- < S2O62-
  3. S2O42- < S2O62- < SO32-
  4. S2O62- < S2O42- < SO32-
AIPMT 2003
4

Which reaction is not feasible?

  1. 2KI + Br2 2KBr + I2
  2. 2KBr + I2 2KI + Br2
  3. 2KBr + Cl2 2KCl + Br2
  4. 2H2O + 2F2 4HF + O2
AIPMT 2002
5

Oxidation numbers of A, B, C are +2, +5 and -2 respectively. Possible formula of compound is

  1. A2(BC2)2
  2. A3(BC4)2
  3. A2(BC3)2
  4. A3(B2C)2
AIPMT 2000

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