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p-Block Elements (Group 15–18) · Question 53

AIPMT 2006MCQMedium📈 Topic in 50% papers+4−1
1

Which one of the following orders is not in accordance with the property stated against it ?

  1. F2 > Cl2 > Br2 > I2 : Bond dissociation energy
  2. F2 > Cl2 > Br2 > I2 : Oxidising power
  3. HI > HBr > HCl > HF : Acidic property in water
  4. F2 > Cl2 > Br2 > I2 : Electronegativity

Answer

(1) F2 > Cl2 > Br2 > I2 : Bond dissociation energy

Solution

As per NCERT, the bond dissociation enthalpy of the halogens follows the order Cl2 > Br2 > F2 > I2.

∵ In F2 the small size of fluorine causes strong repulsion between the lone pairs of the two F atoms, so the F–F bond is weaker than the Cl–Cl and Br–Br bonds.

⇒ Order (1) is not correct.

Oxidising power: F2 > Cl2 > Br2 > I2 (correct).

Acidic strength in water: HI > HBr > HCl > HF, as H–X bond strength decreases down the group (correct).

Electronegativity: F > Cl > Br > I (correct).

Answer: (1)

AIPMT 2006

Keep practising — p-Block Elements (Group 15–18)

2

Which one of the following orders is not in accordance with the property stated against it?

  1. F2 > Cl2 > Br2 > I2 : Bond dissociation energy
  2. F2 > Cl2 > Br2 > I2 : Oxidising power
  3. HI > HBr > HCl > HF : Acidic property in water
  4. F2 > Cl2 > Br2 > I2 : Electronegativity.
AIPMT 2006
3

Which one of the following oxides is expected to exhibit paramagnetic behaviour?

  1. CO2
  2. SiO2
  3. SO2
  4. ClO2
AIPMT 2005
4

What is the correct relationship between the pH of isomolar solutions of sodium oxide, Na2O (pH1), sodium sulphide, Na2S (pH2), sodium selenide, Na2Se (pH3) and sodium telluride Na2Te (pH4)?

  1. pH1 > pH2 > pH3 > pH4
  2. pH1 > pH2 pH3 > pH4
  3. pH1 < pH2 < pH3 < pH4
  4. pH1 < pH2 < pH3 pH4
AIPMT 2005
5

Which one of the following orders correctly represents the increasing acid strengths of the given acids?

  1. HOClO < HOCl < HOClO3 < HOClO2
  2. HOClO3 < HOClO2 < HOClO < HOCl
  3. HOClO2 < HOClO3 < HOClO < HOCl
  4. HOCl < HOClO < HOClO2 < HOClO3
AIPMT 2005
6

Which one of the following statements is not true?

  1. Among halide ions, iodide is the most powerful reducing agent.
  2. Fluorine is the only halogen that does not show a variable oxidation state.
  3. HOCl is a stronger acid than HOBr.
  4. HF is a stronger acid than HCl.
AIPMT 2003
7

Which of the following statement is true?

  1. Silicon exhibits 4 coordination number in its compounds
  2. Bond energy of F2 is less than Cl2
  3. Mn(III) oxidation state is more stable than Mn(II) in aqueous state
  4. Elements of 15th group show only +3 and +5 oxidation states
AIPMT 2002
8

Zn gives H2 gas with H2SO4 and HCl but not with HNO3 because

  1. Zn acts as oxidising agent when it reacts with HNO3
  2. HNO3 is weaker acid than H2SO4 and HCl
  3. In electrochemical series Zn is above hydrogen
  4. NO3- is reduced in preference to hydronium ion.
AIPMT 2002
9

Nitrogen forms N2, but phosphorus does not form P2, however, it exists as P4, reason is

  1. triple bond present between phosphorus atoms
  2. p - p bonding is weak
  3. p - p bonding is strong
  4. multiple bonds form easily.
AIPMT 2001
10

Which statement is wrong ?

  1. Bond energy of F2 > Cl2
  2. Electronegativity of F > Cl
  3. F is more oxidising than Cl
  4. Electron affinity of Cl > F
AIPMT 2000
11

Which compound has planar structure?

  1. XeF4
  2. XeOF2
  3. XeO2F2
  4. XeO4
AIPMT 2000

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