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Structure of Atom · Question 19

NEET (UG) 2019MCQEasy📈 Topic in 12% papers+4−1
1

4d, 5p, 5f and 6p orbitals are arranged in the order of decreasing energy. The correct option is :

  1. 6p > 5f > 4d > 5p
  2. 5f > 6p > 4d > 5p
  3. 5f > 6p > 5p > 4d
  4. 6p > 5f > 5p > 4d

Answer

(3) 5f > 6p > 5p > 4d

Solution

Use the (n + l) rule: higher (n + l) means higher energy; for equal (n + l), the orbital with higher n has higher energy.

4d: n + l = 4 + 2 = 6

5p: n + l = 5 + 1 = 6

5f: n + l = 5 + 3 = 8

6p: n + l = 6 + 1 = 7

∵ 4d and 5p both have (n + l) = 6, 5p (higher n) has higher energy than 4d.

∴ Decreasing energy: 5f > 6p > 5p > 4d

Answer: (3)

NEET (UG) 2019

Keep practising — Structure of Atom

2

Which of the following series of transitions in the spectrum of hydrogen atom falls in visible region?

  1. Paschen series
  2. Brackett series
  3. Lyman series
  4. Balmer series
NEET (UG) 2019
3

Which one is a wrong statement?

  1. Total orbital angular momentum of electron in s-orbital is equal to zero.
  2. An orbital is designated by three quantum numbers while an electron in an atom is designated by four quantum numbers
  3. The electronic configuration of N atom is [figure]
  4. The value of m for dz2 is zero.
NEET 2018
4

Which one is the wrong statement ?

  1. The uncertainty principle is E t h4
  2. Half filled and fully filled orbitals have greater stability due to greater exchange energy, greater symmetry and more balanced arrangement.
  3. The energy of 2s-orbital is less than the energy of 2p-orbital in case of hydrogen like atoms.
  4. de-Broglie's wavelength is given by = hmv, where m = mass of the particle, v = group velocity of the particle.
NEET 2017
5

Two electrons occupying the same orbital are distinguished by

  1. azimuthal quantum number
  2. spin quantum number
  3. principal quantum number
  4. magnetic quantum number
NEET 2016 (Phase 1)
6

How many electrons can fit in the orbital for which n = 3 and l = 1?

  1. 2
  2. 6
  3. 10
  4. 14
NEET 2016 (Phase 2)
7

Which of the following pairs of d-orbitals will have electron density along the axes ?

  1. dz2, dxz
  2. dxz, dyz
  3. dz2, dx2-y2
  4. dxy, dx2-y2
NEET 2016 (Phase 2)
8

Which is the correct order of increasing energy of the listed orbitals in the atom of titanium ? (At. no. Z = 22)

  1. 4s 3s 3p 3d
  2. 3s 3p 3d 4s
  3. 3s 3p 4s 3d
  4. 3s 4s 3p 3d
AIPMT 2015
9

The number of d-electrons in Fe2+ (Z = 26) is not equal to the number of electrons in which one of the following ?

  1. d-electrons in Fe (Z = 26)
  2. p-electrons in Ne (Z = 10)
  3. s-electrons in Mg (Z = 12)
  4. p-electrons in Cl (Z = 17)
AIPMT 2015 (Cancelled)
10

The angular momentum of electron in 'd' orbital is equal to

  1. 2 3
  2. 0
  3. 6
  4. 2
AIPMT 2015 (Cancelled)
11

What is the maximum number of orbitals that can be identified with the following quantum numbers? n = 3, l = 1, ml = 0

  1. 1
  2. 2
  3. 3
  4. 4
AIPMT 2014

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