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Chemical Kinetics · Question 4

JEE Advanced 2024 Paper 1NumericalEasy📈 Topic in 17% papers+4
1

Consider the following reaction, 2H2(g) + 2NO(g) N2(g) + 2H2O(g) which follows the mechanism given below: 2NO(g) k-1 k1 N2O2(g) (fast equlibrium) N2O2(g) + H2(g) k2 N2O(g) + H2O(g) (slow reaction) N2O(g) + H2(g) k3 N2(g) + H2O(g) (fast reaction) The order of the reaction is .

Answer

3

Solution

Rate is decided by the slow step: rate = k2[N2O2][H2].

From the fast equilibrium: K = k1k-1 = [N2O2][NO]2 [N2O2] = K[NO]2.

Rate = k2K[NO]2[H2]

Order = 2 + 1 = 3

Answer: 3

JEE Advanced 2024 Paper 1

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2

A sample initially contains only U-238 isotope of uranium. With time, some of the U-238 radioactively decays into Pb-206 while the rest of it remains undisintegrated. When the age of the sample is P 108 years, the ratio of mass of Pb-206 to that of U-238 in the sample is found to be 7. The value of P is . [Given: Half-life of U-238 is 4.5 109 years; e 2 = 0.693]

JEE Advanced 2024 Paper 2

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