The correct sequence of electron gain enthalpy of the elements listed below is Choose the most appropriate from the options given below:
- A > D > C > B
- A > D > B > C
- D > C > B > A
- C > B > D > A
Answer
(2) A > D > B > C
Solution
egH (kJ mol-1):
Ar = +96, S = −200, Br = −325, F = −328
∵ Ar (noble gas, stable ns2np6) must take the electron into a new shell ⇒ positive value
∵ F is small, so its compact 2p subshell repels the incoming electron ⇒ only slightly more negative than Br
⇒ Ar > S > Br > F ⇒ A > D > B > C
Answer: (2)