The correct statements from the following are : Choose the correct answer from the options given below :
- A, B, D and E only
- A, C and D only
- A, B, C and E
- B, D and E only
Answer
(1) A, B, D and E only
Solution
As per NCERT, the stability of the +1 oxidation state increases down group 13 because of the inert pair effect.
(A) Tl3+ readily changes to Tl+ (E Tl3+/Tl = +1.26 V), so it is a powerful oxidising agent. Correct.
(B) E Al3+/Al = -1.66 V, so Al3+ is not reduced easily. Correct.
(C) Tl3+ is not stable in solution (it is an oxidising agent). Incorrect.
(D) Due to the inert pair effect, Tl+ is more stable than Tl3+. Correct.
(E) Al3+ and Tl+ are the stable states of Al and Tl. Correct.
A, B, D and E are correct.
Answer: (1)