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Organic Chemistry – Some Basic Principles and Techniques · Question 34

JEE Main 2025 (Online) 2nd April Evening ShiftMCQEasy📈 Topic in 3% papers+4−1
1

In 3,3-dimethylhex-1-en-4-yne, there are sp3, sp2 and sp hybridised carbon atoms respectively.

  1. 4, 2, 2
  2. 2, 4, 2
  3. 3, 3, 2
  4. 2, 2, 4

Answer

(1) 4, 2, 2

Solution

Structure: 1CH2= 2CH- 3C(CH3)2- 4C 5C- 6CH3

sp3 (only single bonds): C-3, C-6 and the two -CH3 carbons = 4

sp2 (double-bonded): C-1, C-2 = 2

sp (triple-bonded): C-4, C-5 = 2

4, 2, 2

Answer: (1)

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2

Match List - I with List - II. Choose the correct answer from the options given below :

  1. (A)-(II), (B)-(III), (C)-(IV), (D)-(I)
  2. (A)-(II), (B)-(III), (C)-(I), (D)-(IV)
  3. (A)-(III), (B)-(IV), (C)-(I), (D)-(II)
  4. (A)-(III), (B)-(II), (C)-(I), (D)-(IV)
JEE Main 2025 (Online) 29th January Morning Shift
3

Total number of nucleophiles from the following is : NH3, PhSH, (H3C)2S, H2C=CH2, OH, H3O , (CH3)2 CO, [figure]

  1. 4
  2. 6
  3. 5
  4. 7
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4

The correct order of stability of following carbocations is : [figure]

  1. A > B > C > D
  2. C > B > A > D
  3. B > C > A > D
  4. C > A > B > D
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