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General Principles of Isolation of Elements · Question 15

AIPMT 2012 (Prelims)MCQEasy📈 Topic in 25% papers+4−1
1

In the extraction of copper from its sulphide ore, the metal is finally obtained by the reduction of cuprous oxide with

  1. carbon monoxide
  2. copper (I) sulphide
  3. sulphur dioxide
  4. iron (II) sulphide.

Answer

(2) copper (I) sulphide

Solution

As per NCERT, the copper matte is put in a silica-lined converter; part of Cu2S is oxidised to Cu2O, which then reacts with the remaining Cu2S (self-reduction):

2Cu2S + 3O2 2Cu2O + 2SO2

2Cu2O + Cu2S 6Cu + SO2

Cuprous oxide is reduced by copper(I) sulphide.

Answer: (2)

Out of syllabusAIPMT 2012 (Prelims)

Keep practising — General Principles of Isolation of Elements

2

Aluminium is extracted from alumina (Al2O3) by electrolysis of a molten mixture of

  1. Al2O3 + HF + NaAlF4
  2. Al2O3 + CaF2 + NaAlF4
  3. Al2O3 + Na3AlF6 + CaF2
  4. Al2O3 + KF + Na3AlF6
Out of syllabusAIPMT 2012 (Prelims)
3

Which one of the following is a mineral of iron?

  1. Malachite
  2. Cassiterite
  3. Pyrolusite
  4. Magnetite
Out of syllabusAIPMT 2012 (Prelims)
4

The following reactions take place in the blast furnace in the preparation of impure iron. Identify the reaction pertaining to the formation of the slag.

  1. Fe2O3(s) + 3CO(g) 2Fe(l) + 3CO2(g)
  2. CaCO3(s) CaO(s) + CO2(g)
  3. CaO(s) + SiO2(s) CaSiO3(s)
  4. 2C(s) + O2(g) 2CO(g)
Out of syllabusAIPMT 2011 (Mains)
5

Which of the following elements is present as the impurity to the maximum extent in pig iron?

  1. Manganese
  2. Carbon
  3. Silicon
  4. Phosphorus
Out of syllabusAIPMT 2011 (Prelims)
6

Which of the following pairs of metals is purified by van Arkel method?

  1. Ga and In
  2. Zr and Ti
  3. Ag and Au
  4. Ni and Fe
Out of syllabusAIPMT 2011 (Prelims)
7

Sulphide ores of metals are usually concentrated by froth flotation process. Which one of the following sulphide ores offers an exception and is concentrated by chemical leaching?

  1. Galena
  2. Copper pyrite
  3. Sphalerite
  4. Argentite
Out of syllabusAIPMT 2007
8

Which of the following statements about the advantage of roasting of sulphide ore before reduction is not true?

  1. The fG of the sulphide is greater than those for CS2 and H2S.
  2. The fG is negative for roasting of sulphide ore to oxide.
  3. Roasting of the sulphide to the oxide is thermodynamically feasible.
  4. Carbon and hydrogen are suitable reducing agents for metal sulphides.
Out of syllabusAIPMT 2007
9

The mass of carbon anode consumed (giving only carbon dioxide) in the production of 270 kg of aluminium metal from bauxite by the Hall process is (Atomic mass : Al = 27)

  1. 270 kg
  2. 540 kg
  3. 90 kg
  4. 180 kg
AIPMT 2005
10

The method of zone refining of metals is based on the principle of

  1. greater mobility of the pure metal than that of the impurity
  2. higher melting point of the impurity than that of the pure metal
  3. greater noble character of the solid metal than that of the impurity
  4. greater solubility of the impurity in the molten state than in the solid
Out of syllabusAIPMT 2003

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