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Solutions · Question 19

NEET 2017MCQEasy📈 Topic in 0% papers+4−1
1

If molality of the dilute solution is doubled, the value of molal depression constant (Kf) will be

  1. halved
  2. tripled
  3. unchanged
  4. doubled.

Answer

(3) unchanged

Solution

Tf = Kf m

As per NCERT, Kf = R M1 Tf21000 fusH, which depends only on the nature of the solvent.

⇒ On doubling the molality, Tf doubles but Kf remains unchanged.

Answer: (3)

NEET 2017

Keep practising — Solutions

2

Which of the following is dependent on temperature?

  1. Molarity
  2. Mole fraction
  3. Weight percentage
  4. Molality
NEET 2017
3

Which of the following statements about the composition of the vapour over an ideal 1 : 1 molar mixture of benzene and toluene is correct? Assume that the temperature is constant at 25 . (Given, vapour pressure data at 25 , benzene = 12.8 kPa, toluene = 3.85 kPa)

  1. The vapour will contain equal amounts of benzene and toluene.
  2. Not enough information is given to make a prediction.
  3. The vapour will contain a higher percentage of benzene.
  4. The vapour will contain a higher percentage of toluene
NEET 2016 (Phase 1)
4

At 100 the vapour pressure of a solution of 6.5 g of a solute in 100 g water is 732 mm. If Kb = 0.52, the boiling point of this solution will be

  1. 102
  2. 103
  3. 101
  4. 100
NEET 2016 (Phase 1)
5

The van't Hoff factor (i) for a dilute aqueous solution of the strong electrolyte barium hydroxide is

  1. 0
  2. 1
  3. 2
  4. 3
NEET 2016 (Phase 2)
6

Which one of the following is incorrect for ideal solution?

  1. Hmix = 0
  2. Umix = 0
  3. P = Pobs - Pcalculated by Raoult's law = 0
  4. Gmix = 0
NEET 2016 (Phase 2)
7

What is the mole fraction of the solute in a 1.00 m aqueous solution?

  1. 1.770
  2. 0.0354
  3. 0.0177
  4. 0.177
AIPMT 2015
8

The boiling point of 0.2 mol kg-1 solution of X in water is greater than equimolal solution of Y in water. Which one of the following statements is true in this case?

  1. Molecular mass of X is less than the molecular mass of Y.
  2. Y is undergoing dissociation in water while X undergoes no change.
  3. X is undergoing dissociation in water.
  4. Molecular mass of X is greater than the molecular mass of Y.
AIPMT 2015 (Cancelled)
9

Which one of the following electrolytes has the same value of van't Hoff factor (i) as that of Al2(SO4)3 (if all are 100% ionised)?

  1. Al(NO3)3
  2. K4[Fe(CN)6]
  3. K2SO4
  4. K3[Fe(CN)6]
AIPMT 2015 (Cancelled)
10

Which of them is not equal to zero for an ideal solution?

  1. Vmix
  2. P = Pobserved - PRaoult
  3. Hmix
  4. Smix
AIPMT 2015 (Cancelled)
11

Of the following 0.10 m aqueous solutions, which one will exhibit the largest freezing point depression?

  1. KCl
  2. C6H12O6
  3. Al2(SO4)3
  4. K2SO4
AIPMT 2014

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