Equilibrium · Question 62

The reaction, 2A(g) + B(g) 3C(g) + D(g) is begun with the concentrations of A and B both at an initial value of 1.00 M. When equilibrium is reached, the concentration of D is measured and found to be 0.25 M. The value for the equilibrium constant for this reaction is given by the expression

1. [(0.75)3(0.25)] [(1.00)2(1.00)]
2. [(0.75)3(0.25)] [(0.50)2(0.75)]
3. [(0.75)3(0.25)] [(0.50)2(0.25)]
4. [(0.75)3(0.25)] [(0.75)2(0.25)]

If pH of a saturated solution of Ba(OH)2 is 12, the value of its Ksp is

1. 4.00 10-6 M3
2. 4.00 10-7 M3
3. 5.00 10-6 M3
4. 5.00 10-7 M3

What is [H+] in mol/L of a solution that is 0.20 M in CH3COONa and 0.10 M in CH3COOH? Ka for CH3COOH = 1.8 10-5

1. 3.5 10-4
2. 1.1 10-5
3. 1.8 10-5
4. 9.0 10-6

In which of the following equilibrium Kc and Kp are not equal?

1. 2NO(g) N2(g) + O2(g)
2. SO2(g) + NO2(g) SO3(g) + NO(g)
3. H2(g) + I2(g) 2HI(g)
4. 2C(s) + O2(g) 2CO(g)

In a buffer solution containing equal concentration of B- and HB, the Kb for B- is 10-10. The pH of buffer solution is

1. 10
2. 7
3. 6
4. 4

The dissociation constants for acetic acid and HCN at 25 are 1.5 10-5 and 4.5 10-10 respectively. The equilibrium constant for the equilibrium CN- + CH3COOH HCN + CH3COO- would be

1. 3.3 10-5
2. 3.3 10-4
3. 3.3 104
4. 3.3 105

Which of the following molecules acts as a Lewis acid?

1. (CH3)2O
2. (CH3)3P
3. (CH3)3N
4. (CH3)3B

The ionization constant of ammonium hydroxide is 1.77 10-5 at 298 K. Hydrolysis constant of ammonium chloride is

1. 6.50 10-12
2. 5.65 10-13
3. 5.65 10-12
4. 5.65 10-10

What is the [OH-] in the final solution prepared by mixing 20.0 mL of 0.050 M HCl with 30.0 mL of 0.10 M Ba(OH)2?

1. 0.40 M
2. 0.0050 M
3. 0.12 M
4. 0.10 M

The dissociation equilibrium of a gas AB2 can be represented as: 2AB2(g) 2AB(g) + B2(g) The degree of dissociation is x and is small compared to 1. The expression relating the degree of dissociation (x) with equilibrium constant Kp and total pressure P is

1. (2Kp/P)1/2
2. (Kp/P)
3. (2Kp/P)
4. (2Kp/P)1/3