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Coordination Compounds · Question 98

AIPMT 2001MCQEasy📈 Topic in 25% papers+4−1
1

Which of the following will exhibit maximum ionic conductivity?

  1. K4[Fe(CN)6]
  2. [Co(NH3)6]Cl3
  3. [Cu(NH3)4]Cl2
  4. [Ni(CO)4]

Answer

(1) K4[Fe(CN)6]

Solution

Ionic conductivity increases with the number of ions given in solution.

K4[Fe(CN)6] 4K+ + [Fe(CN)6]4- 5 ions

[Co(NH3)6]Cl3 [Co(NH3)6]3+ + 3Cl- 4 ions

[Cu(NH3)4]Cl2 [Cu(NH3)4]2+ + 2Cl- 3 ions

[Ni(CO)4] is neutral no ions

K4[Fe(CN)6] shows the maximum ionic conductivity.

Answer: (1)

AIPMT 2001

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2

In qualitative analysis of second group in laboratory, H2S gas is passed in acidic medium for precipitation. When Cu2+ and Cd2+ react with KCN, then for product, true statement is

  1. K2[Cu(CN)4] – more stable; K2[Cd(CN)4] – less stable
  2. K2[Cu(CN)4] – less stable; K2[Cd(CN)4] – more stable
  3. K3[Cu(CN)4] – more stable; K2[Cd(CN)4] – less stable
  4. K3[Cu(CN)4] – less stable; K3[Cd(CN)4] – more stable
AIPMT 2000
3

Shape of Fe(CO)5 is

  1. octahedral
  2. square planar
  3. trigonal bipyramidal
  4. square pyramidal
AIPMT 2000
4

Which complex compound will give four isomers?

  1. [Fe(en)3]Cl3
  2. [Co(en)(NH3)2Cl2]Cl
  3. [Fe(PPh3)3NH3ClBr]Cl
  4. [Co(PPh3)3Cl]Cl3
AIPMT 2000

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