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JEE Advanced 2025 Paper 2NumericalMedium📈 Topic in 17% papers+4
1

At 300 K, an ideal dilute solution of a macromolecule exerts osmotic pressure that is expressed in terms of the height (h) of the solution (density = 1.00 g cm-3) where h is equal to 2.00 cm. If the concentration of the dilute solution of the macromolecule is 2.00 g dm-3, the molar mass of the macromolecule is calculated to be X 104 g mol-1. The value of X is . Use: Universal gas constant (R) = 8.3 J K-1 mol-1 and acceleration due to gravity (g) = 10 m s-2

Answer

2.4 to 2.55

Solution

= h g = wM RTV (SI units)

= 0.02 m 1000 kg m-3 10 m s-2 = 200 Pa

Concentration = 2.00 g dm-3 = 2000 g m-3

M = 2000 8.3 300200 = 24900 g mol-1 = 2.49 104 g mol-1

Answer: 2.49

JEE Advanced 2025 Paper 2

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2

Vessel-1 contains w2 g of a non-volatile solute X dissolved in w1 g of water. Vessel-2 contains w2 g of another non-volatile solute Y dissolved in w1 g of water. Both the vessels are at the same temperature and pressure. The molar mass of X is 80% of that of Y. The van’t Hoff factor for X is 1.2 times of that of Y for their respective concentrations. The elevation of boiling point for solution in Vessel-1 is % of the solution in Vessel-2.

JEE Advanced 2024 Paper 2

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