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Aldehydes, Ketones and Carboxylic Acids

JEE Main 2024 (Online) 6th April Evening ShiftMCQEasy📈 Topic in 15% papers+4−1
Ques. 1JEE Main 2024, 6 April (Evening Shift)

Consider the given reaction, identify the major product P. CH3-COOH [(iv) H2O/ OH, ](i) LiAlH4 (ii) PCC (iii) HCN/ OH “P”

  1. CH3- OH |CH-COOH
  2. CH3-CH2- O \|C-NH2
  3. CH3- O \|C-CH2CH3
  4. CH3-CH2-CH2-OH

Answer

(1) CH3- OH |CH-COOH

Solution

CH3COOH LiAlH4 CH3CH2OH (–COOH reduced to 1° alcohol)

PCC CH3CHO (PCC stops at the aldehyde)

HCN/ OH CH3- OH |CH-CN (cyanohydrin: nucleophilic addition of CN-)

H2O/ OH, CH3- OH |CH-COOH (–CN hydrolysed to –COOH)

∴ P = 2-hydroxypropanoic acid (lactic acid)

Answer: (1)

Keep practising — Aldehydes, Ketones and Carboxylic Acids

Ques. 2JEE Main 2024, 5 April (Morning Shift)

For the Compounds : (A) H3C-CH2-O-CH2-CH2-CH3 (B) H3C-CH2-CH2-CH2-CH3 (C) CH3-CH2- O \|C-CH2-CH3 (D) H3C- OH |CH-CH2-CH2-CH3 The increasing order of boiling point is : Choose the correct answer from the options given below :

  1. (D) < (C) < (A) < (B)
  2. (B) < (A) < (C) < (D)
  3. (A) < (B) < (C) < (D)
  4. (B) < (A) < (D) < (C)
Ques. 3JEE Main 2024, 5 April (Morning Shift)

Identify 'A' in the following reaction : [figure]

  1. [figure]
  2. [figure]
  3. [figure]
  4. [figure]
Ques. 4JEE Main 2024, 5 April (Evening Shift)

Identify A and B in the given chemical reaction sequence : [figure]

  1. [figure]
  2. [figure]
  3. [figure]
  4. [figure]
Ques. 5JEE Main 2024, 5 April (Evening Shift)

[figure] Consider the above reaction sequence and identify the major product P.

  1. Methanoic acid
  2. Methoxymethane
  3. Methane
  4. Methanal
Ques. 6JEE Main 2024, 5 April (Evening Shift)

The product C in the following sequence of reactions has bonds. [figure]

Ques. 7JEE Main 2024, 5 April (Evening Shift)

In the Claisen-Schmidt reaction to prepare 351 g of dibenzalacetone using 87 g of acetone, the amount of benzaldehyde required is g. (Nearest integer)

Ques. 8JEE Main 2024, 4 April (Morning Shift)

Given below are two statements : In the light of the above statements, choose the most appropriate answer from the options given below :

  1. Both Statement I and Statement II are incorrect
  2. Statement I is correct but Statement II is incorrect
  3. Both Statement I and Statement II are correct
  4. Statement I is incorrect but Statement II is correct
Ques. 9JEE Main 2024, 4 April (Morning Shift)

Identify the product in the following reaction: [figure]

  1. [figure]
  2. [figure]
  3. [figure]
  4. [figure]
Ques. 10JEE Main 2024, 4 April (Morning Shift)

The number of the correct reaction(s) among the following is . [figure]

Ques. 11JEE Main 2024, 4 April (Evening Shift)

[figure] In the above chemical reaction sequence "A" and "B" respectively are

  1. H2O, H+ and NaOH(alc)/I2
  2. O3, Zn/H2O and KMnO4
  3. H2O, H+ and KMnO4
  4. O3, Zn/H2O and NaOH(alc)/I2

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