Hydrocarbons · Question 2

An optically active alkyl bromide C4H9Br, reacts with ethanolic KOH to form major compound [A] which reacts with bromine to give compound [B]. Compound [B] reacts with ethanolic KOH and sodamide to give compound [C]. One molecule of water adds to compound [C] on warming with mercuric sulphate and dilute sulphuric acid at 333 K to form compound [D]. The functional group in compound D will be confirmed by :

1. Haloform test
2. Lucas test
3. Silver mirror test
4. Benedict test

An alkane (Y) requires 8 moles of oxygen for complete combustion and on chlorination with Cl2/h , (Y) gives only one monochlorinated product (Z). The total number of primary carbon atoms in (Y) is .

For the following Friedel Craft's alkylation reaction, which of the statements are correct? [figure] Choose the correct answer from the options given below :

1. A and D only
2. B and C only
3. A and C only
4. B and D only

An alkene (X) on ozonolysis followed by reduction gives following products. H- O \|C-H (2 moles), H- O \|C- O \|C- O \|C-H, CH3- O \|C- O \|C- O \|C-CH3 The alkene (X) is :

1. [figure]
2. [figure]
3. [figure]
4. [figure]

[figure] Compound (X) is subjected to the sequence of reactions as shown above. Molar mass of the major product (Y) formed is g mol-1. (Given molar mass in g mol-1 C : 12, H : 1, O : 16 )

1. 90
2. 118
3. 160
4. 125

One mole of an alkane (x) requires 8 mole oxygen for complete combustion. Sum of number of carbon and hydrogen atoms in the alkane (x) is .

The compound (X) on (i) on heating in the presence of anhydrous AlCl3 and HCl gas gives 2,4-dimethyl pentane (ii) aromatization gives toluene and (iii) cyclisation gives methyl cyclohexane The correct name of compound (X) is:

1. Hept-2-ene
2. Hept-1,3,5-triene
3. Heptane
4. Hept-2,4,6-triene

Given below are two statements for the following reaction sequence. [figure] In the light of the above statements, choose the correct answer from the options given below :

1. Statement I is true but Statement II is false
2. Both Statement I and Statement II are true
3. Statement I is false but Statement II is true
4. Both Statement I and Statement II are false

Ph-CH=CH2 [HBr](PhCOO)2 Product Consider the above reaction Identify the correct statements. Choose the correct answer from the options given below :

1. A & E Only
2. A, B & D Only
3. A, C & E Only
4. C, D & E Only

The reactions which produce alcohol as the product are : Choose the correct answer from the options given below :

1. B, D and E Only
2. A and D Only
3. A, C and E Only
4. C and D Only