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Thermodynamics · Question 39

JEE Main 2025 (Online) 28th January Evening ShiftMCQEasy📈 Topic in 13% papers+4−1
1

[figure] An ideal gas undergoes a cyclic transformation starting from the point A and coming back to the same point by tracing the path A→B→C→D→A as shown in the three cases above. Choose the correct option regarding U :

  1. U(Case-III) > U(Case-II) > U(Case-I)
  2. U(Case-I) > U(Case-II) > U(Case-III)
  3. U(Case-I) = U(Case-II) = U(Case-III)
  4. U(Case-I) > U(Case-III) > U(Case-II)

Answer

(3) U(Case-I) = U(Case-II) = U(Case-III)

Solution

Internal energy U is a state function: its change depends only on the initial and final states, not on the path.

In every case the gas starts at A and returns to the same point A (cyclic process).

U = UA - UA = 0 for each cycle.

(The paths differ only in the work and heat exchanged: q = -w for each cycle.)

U(Case-I) = U(Case-II) = U(Case-III) = 0

Answer: (3)

JEE Main 2025 (Online) 28th January Evening Shift

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2

Consider the following data: Heat of formation of CO2(g) = -393.5 kJ mol-1 Heat of formation of H2O(l) = -286.0 kJ mol-1 Heat of combustion of benzene = -3267.0 kJ mol-1 The heat of formation of benzene is kJ mol-1. (Nearest integer)

JEE Main 2025 (Online) 28th January Evening Shift

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