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Organic Chemistry – Some Basic Principles and Techniques

JEE Main 2024 (Online) 1st February Evening ShiftMCQEasy📈 Topic in 17% papers+4−1
Ques. 1JEE Main 2024, 1 February (Evening Shift)

The functional group that shows negative resonance effect is :

  1. -OH
  2. -OR
  3. -COOH
  4. -NH2

Answer

(3) -COOH

Solution

−R effect: the group pulls π electrons of the conjugated system towards itself (C=O, C≡N, NO2 type groups); a lone pair on the attached atom gives +R.

(A): –OH — lone pair on O donated ⇒ (A) is +R

(B): –OR — lone pair on O donated ⇒ (B) is +R

(C): –COOH — C=O pulls π electrons towards O ⇒ (C) is −R

(D): -NH2 — lone pair on N donated ⇒ (D) is +R

Answer: (3)

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Ques. 2JEE Main 2024, 31 January (Morning Shift)

A species having carbon with sextet of electrons and can act as electrophile is called

  1. pentavalent carbon
  2. carbon free radical
  3. carbanion
  4. carbocation
Ques. 3JEE Main 2024, 31 January (Morning Shift)

Given below are two statements: In the light of the above statements, choose the most appropriate answer from the options given below:

  1. Statement I is incorrect but Statement II is correct.
  2. Statement I is correct but Statement II is incorrect.
  3. Both Statement I and Statement II are correct.
  4. Both Statement I and Statement II are incorrect.
Ques. 4JEE Main 2024, 30 January (Morning Shift)

Which of the following molecule/species is most stable?

  1. [figure]
  2. [figure]
  3. [figure]
  4. [figure]
Ques. 5JEE Main 2024, 30 January (Morning Shift)

Structure of 4-Methylpent-2-enal is :

  1. H2C= H |C- CH3 | H |C-CH2- O \|C-H
  2. CH3-CH2- CH3 |C=CH- O \|C-H
  3. CH3- CH3 |CH-CH=CH- O \|C-H
  4. CH3-CH2-CH= CH3 |C- O \|C-H
Ques. 6JEE Main 2024, 30 January (Evening Shift)

The correct stability order of carbocations is

  1. (CH3)3C > CH3- CH2 > (CH3)2 CH > CH3
  2. (CH3)3 C > (CH3)2 CH > CH3- CH2 > CH3
  3. CH3 > CH3- CH2 > CH3- CH3 | CH > (CH3)3C
  4. CH3 > (CH3)2 CH > CH3- CH2 > (CH3)3 C
Ques. 7JEE Main 2024, 30 January (Evening Shift)

IUPAC name of following compound is : CH3- NH2 |CH-CH2-CN

  1. 2-Aminobutanenitrile
  2. 3-Aminopropanenitrile
  3. 2-Aminopentanenitrile
  4. 3-Aminobutanenitrile
Ques. 8JEE Main 2024, 29 January (Morning Shift)

The difference in energy between the actual structure and the lowest energy resonance structure for a given compound is

  1. electromeric energy
  2. resonance energy
  3. ionization energy
  4. hyperconjugation energy
Ques. 9JEE Main 2024, 29 January (Morning Shift)

The interaction between bond and lone pair of electrons present on an adjacent atom is responsible for

  1. Resonance effect
  2. Electromeric effect
  3. Hyperconjugation
  4. Inductive effect
Ques. 10JEE Main 2024, 29 January (Morning Shift)

Number of compounds among the following which contain sulphur as heteroatom is . Furan, Thiophene, Pyridine, Pyrrole, Cysteine, Tyrosine

Ques. 11JEE Main 2024, 29 January (Evening Shift)

According to IUPAC system, the compound [figure] is named as

  1. Cyclohex-2-en-1-ol
  2. 1-Hydroxyhex-2-ene
  3. Cyclohex-1-en-3-ol
  4. Cyclohex-1-en-2-ol

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