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Amines · Question 35

NEET 2013 (Karnataka)MCQMedium📈 Topic in 62% papers+4−1
1

On hydrolysis of a "compound", two compounds are obtained. One of which on treatment with sodium nitrite and hydrochloric acid gives a product which does not respond to iodoform test. The second one reduces Tollens reagent and Fehling's solution. The "compound" is

  1. CH3CH2CH2NC
  2. CH3CH2CH2CN
  3. CH3CH2CH2ON=O
  4. CH3CH2CH2CON(CH3)2

Answer

(1) CH3CH2CH2NC

Solution

Acid hydrolysis of propyl isocyanide:

CH3CH2CH2NC + 2H2O H+ CH3CH2CH2NH2 + HCOOH

(i) Propan-1-amine with NaNO2 + HCl (nitrous acid) gives propan-1-ol:

CH3CH2CH2NH2 + HNO2 CH3CH2CH2OH + N2 + H2O

⇒ propan-1-ol has no CH3CH(OH)- group ⇒ no iodoform test.

(ii) Methanoic acid (HCOOH) has an aldehydic H ⇒ reduces Tollens' reagent and Fehling's solution.

∴ The "compound" is CH3CH2CH2NC.

Answer: (1)

NEET 2013 (Karnataka)

Keep practising — Amines

2

Some reactions of amines are given. Which one is not correct?

  1. [figure]
  2. CH3CH2NH2 + HNO2 CH3CH2OH + N2
  3. CH3NH2 + C6H5SO2Cl CH3NHSO2C6H5
  4. (CH3)2NH + NaNO2 + HCl (CH3)2N-N=O
NEET 2013 (Karnataka)
3

An organic compound (C3H9N) (A), when treated with nitrous acid, gave an alcohol and N2 gas was evolved. (A) on warming with CHCl3 and caustic potash gave (C) which on reduction gave isopropylmethylamine. Predict the structure of (A)

  1. [figure]
  2. CH3CH2-NH-CH3
  3. [figure]
  4. CH3CH2CH2-NH2
AIPMT 2012 (Mains)
4

An organic compound A on treatment with NH3 gives B, which on heating gives C. C when treated with Br2 in the presence of KOH produces ethyl amine. Compound A is

  1. CH3COOH
  2. CH3CH2CH2COOH
  3. [figure]
  4. CH3CH2COOH
AIPMT 2011 (Mains)
5

Which of the following compounds is most basic?

  1. [figure]
  2. [figure]
  3. [figure]
  4. [figure]
AIPMT 2011 (Mains)
6

In a set of reactions m-bromobenzoic acid gave a product D. Identify the product D. [figure]

  1. [figure]
  2. [figure]
  3. [figure]
  4. [figure]
AIPMT 2011 (Prelims)
7

What is the product obtained in the following reaction? [figure]

  1. [figure]
  2. [figure]
  3. [figure]
  4. [figure]
AIPMT 2011 (Prelims)
8

Match the compounds given in List-I with their characteristic reactions given in List-II. Select the correct option.

  1. A-(ii), B-(i), C-(iv), D-(iii)
  2. A-(iii), B-(ii), C-(i), D-(iv)
  3. A-(ii), B-(iii), C-(i), D-(iv)
  4. A-(iv), B-(ii), C-(iii), D-(i)
AIPMT 2010 (Mains)
9

Acetamide is treated with the following reagents separately. Which one of these would yield methyl amine?

  1. NaOH/Br2
  2. Sodalime
  3. Hot conc. H2SO4
  4. PCl5
AIPMT 2010 (Prelims)
10

Which of the following statements about primary amines is false?

  1. Alkyl amines are stronger bases than aryl amines.
  2. Alkyl amines react with nitrous acid to produce alcohols.
  3. Aryl amines react with nitrous acid to produce phenols.
  4. Alkyl amines are stronger bases than ammonia.
AIPMT 2010 (Prelims)
11

Aniline in a set of the following reactions yielded a coloured product Y. [figure] The structure of 'Y' would be

  1. [figure]
  2. [figure]
  3. [figure]
  4. [figure]
AIPMT 2010 (Prelims)

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