Identify the incorrect statement from the following:
- Oxygen exhibits only −2 oxidation state.
- The order of catenation property of Group 14 elements is C Si > Ge Sn.
- Carbon has the ability to form pπ–pπ multiple bond with itself.
- ECl3 (E = B and Al) is a monomer when E = B and a dimer when E = Al.
Answer
(1) Oxygen exhibits only −2 oxidation state.
Solution
Oxygen shows −2 in most compounds, but −1 in peroxides (H2O2), −½ in superoxides (KO2), +2 in OF2 and +1 in O2F2 ⇒ "only −2" is incorrect.
Other statements are correct (NCERT): catenation C Si > Ge Sn; carbon forms pπ–pπ multiple bonds with itself; BCl3 is monomeric while AlCl3 dimerises (Al2Cl6).
Answer: (1)