Which of the following statements about hydrogen is incorrect?
- Hydronium ion, H3O+ exists freely in solution.
- Dihydrogen does not act as a reducing agent.
- Hydrogen has three isotopes of which tritium is the most common.
- Hydrogen never acts as cation in ionic salts.
Answer
(2) Dihydrogen does not act as a reducing agent., (3) Hydrogen has three isotopes of which tritium is the most common.
Solution
(1) A free proton (H+) cannot exist in water; it combines with a water molecule to form the hydronium ion H3O+, which exists in solution. Correct.
(2) As per NCERT, dihydrogen is a reducing agent, e.g. it reduces metal oxides: CuO + H2 Cu + H2O. Incorrect.
(3) Hydrogen has three isotopes: protium, deuterium and tritium. Protium is the most common (about 99.985%), while tritium is radioactive and occurs only in traces. Incorrect.
(4) H+ (a bare proton) is too small to exist as a cation in an ionic lattice, so hydrogen does not act as a cation in ionic salts. Correct.
The incorrect statements are (2) and (3).
Answer: (2), (3)