Which among the following react with Hinsberg's reagent? Choose the correct answer from the options given below :
- A, C and E only
- A, B and E only
- C and D only
- B and D only
Answer
(1) A, C and E only
Solution
Concept: Hinsberg's reagent (C6H5SO2Cl) reacts only with amines having N–H (1° and 2°), not 3°.
A. aniline (1°) ✓
[figure]
E. diphenylamine (2°) ✓
[figure]
C. methylamine (1°) ✓
B, D: 3° amines (no N–H) ✗
∴ A, C and E only
Answer: (1)