Given below are four compounds : (a) n-propyl chloride (b) isopropyl chloride (c) sec-butyl chloride (d) neopentyl chloride Percentage of carbon in the one which exhibits optical isomerism is :
- 46
- 40
- 52
- 56
Answer
(3) 52
Solution
(a) CH3-CH2-CH2-Cl: no chiral carbon
(b) (CH3)2CH-Cl: two identical CH3 groups on C – no chiral carbon
(c) CH3-CH2-CH(Cl)-CH3: C-2 carries H, Cl, CH3 and C2H5 chiral, shows optical isomerism
(d) (CH3)3C-CH2-Cl: no chiral carbon
sec-Butyl chloride, C4H9Cl: molar mass = 4(12) + 9(1) + 35.5 = 92.5 g mol-1
\% C = 4892.5 100 = 51.9 52
Answer: (3)