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Chemical Bonding and Molecular Structure

Previous year questions with solutions · 2025 – 2026

35Questions
30Papers covered
4.63% ↑6.9%Weightage in 2026
’25
’26
Year-wise statistics questions · papers · average per paper · weightage
YearQuestionsPapersAvg / paperWeightage
202622191.24.63% ↑6.9%
202513121.14.33%

8 questions · newest paper first

1

Bromine trifluoride autoionizes to form BrF2 and BrF4 . The shapes of the cation and anion are respectively and .

  1. bent, square planar
  2. linear, square planar
  3. bent, see-saw
  4. linear, tetrahedral
JEE Main 2026 (Online) 8th April Evening Shift
2

SF4 is isostructural with : Choose the correct answer from the options given below :

  1. C Only
  2. C and E Only
  3. A and D Only
  4. B and E Only
JEE Main 2026 (Online) 2nd April Evening Shift
3

Identify the molecule (X) with maximum number of lone pairs of electrons (obtained using Lewis dot structure) among HNO3, H2SO4, NF3 and O3. Choose the correct bond angle made by the central atom of the molecule (X).

  1. 107
  2. 102
  3. 120
  4. 116
JEE Main 2026 (Online) 23rd January Morning Shift
4

Which statements are NOT TRUE about XeO2F2? Choose the correct answer from the options given below :

  1. B, D and E Only
  2. B and D Only
  3. B, C and E Only
  4. A and D Only
JEE Main 2026 (Online) 23rd January Evening Shift
5

Given below are two statements : In the light of the above statements, choose the correct answer from the options given below:

  1. Both Statement I and Statement II are true
  2. Statement I is true but Statement II is false
  3. Statement I is false but Statement II is true
  4. Both Statement I and Statement II are false
JEE Main 2026 (Online) 21st January Morning Shift
6

Given below are two statements: In the light of the above statements, choose the most appropriate answer from the options given below:

  1. Both Statement I and Statement II are correct
  2. Both Statement I and Statement II are incorrect
  3. Statement I is correct but Statement II is incorrect
  4. Statement I is incorrect but Statement II is correct
JEE Main 2025 (Online) 4th April Evening Shift
7

A molecule with the formula AX4Y has all its elements from p-block. Element A is rarest, monoatomic, non-radioactive from its group and has the lowest ionization enthalpy value among A, X and Y. Elements X and Y have first and second highest electronegativity values respectively among all the known elements. The shape of the molecule is:

  1. Pentagonal planar
  2. Square pyramidal
  3. Trigonal bipyramidal
  4. Octahedral
JEE Main 2025 (Online) 2nd April Morning Shift
8

The molecules having square pyramidal geometry are

  1. BrF5 & PCl5
  2. SbF5 & PCl5
  3. BrF5 & XeOF4
  4. SbF5 & XeOF4
JEE Main 2025 (Online) 28th January Morning Shift