Chemical Kinetics

Given below are two statements : R = 8.314 J K-1 mol-1 and 1 cal = 4.2 J In the light of the above statements, choose the correct answer from the options given below :

1. Both Statement I and Statement II are true
2. Both Statement I and Statement II are false
3. Statement I is true but Statement II is false
4. Statement I is false but Statement II is true

Decomposition of a hydrocarbon follows the equation k = (5.5 1011 s-1) e-28000 K/T. The activation energy of reaction is kJ mol-1. (Nearest Integer) Given : R = 8.3 J K-1 mol-1

For reaction A P, rate constant k = 1.5 103 s-1 at 27°C If activation energy for the above reaction is 60 kJ mol-1, then the temperature (in °C) at which rate constant, k = 4.5 103 s-1 is . (Nearest integer) Given : log 2 = 0.30, log 3 = 0.48, R = 8.3 J K-1 mol-1, ln 10 = 2.3

A → B (first reaction) C → D (second reaction) Consider the above two first-order reactions. The rate constant for first reaction at 500 K is double of the same at 300 K. At 500 K, 50% of the reaction becomes complete in 2 hours. The activation energy of the second reaction is half of that of first reaction. If the rate constant at 500 K of the second reaction becomes double of the rate constant of first reaction at the same temperature; then rate constant for the second reaction at 300 K is 10-1 hour-1 (nearest integer).

The temperature at which the rate constants of the given below two gaseous reactions become equal is K. (Nearest integer) X Y, k1 = 106 e -30000T P Q, k2 = 104 e -24000T Given : 10 = 2.303

Correct statements regarding Arrhenius equation among the following are : Choose the correct answer from the options given below :

1. A and B Only
2. B and D Only
3. B and C Only
4. A and C Only

Consider A k1 B and C k2 D are two reactions. If the rate constant (k1) of the A B reaction can be expressed by the following equation 10 k = 14.34 - 1.5 104T/K and activation energy of C D reaction (Ea2) is 15th of the A B reaction (Ea1), then the value of (Ea2) is kJ mol-1. (Nearest Integer)

Pre-exponential factors of two different reactions of same order are identical. Let activation energy of first reaction exceed the activation energy of second reaction by 20 kJ mol-1. If k1 and k2 are the rate constants of first and second reaction respectively at 300 K, then k2k1 will be . (nearest integer) [R = 8.3 J K-1 mol-1]

Consider the following plots of log of rate constant k (log k) vs 1T for three different reactions. The correct order of activation energies of these reactions is : [figure]

1. Ea2 > Ea1 > Ea3
2. Ea1 > Ea3 > Ea2
3. Ea3 > Ea2 > Ea1
4. Ea1 > Ea2 > Ea3

Consider the following statements related to temperature dependence of rate constants. Identify the correct statements. Choose the correct answer from the options given below:

1. A, C and D Only
2. B, D and E Only
3. B and C Only
4. A and B Only