d- and f-Block Elements

The incorrect relationship in the following pairs in relation to ionisation enthalpies is :

1. Mn2+ < Fe2+
2. Mn+ < Mn2+
3. Mn+ < Cr+
4. Fe2+ < Fe3+

The metal ions that have the calculated spin-only magnetic moment value of 4.9 B.M. are : Choose the correct answer from the options given below:

1. A, D and E Only
2. A, B and E Only
3. A, C and E Only
4. B and E Only

Consider the following reactions A + Little amountNaCl + H2SO4 CrO2Cl2 + Side Products CrO2Cl2(Vapour) + NaOH B + NaCl + H2O B + H+ C + H2O The number of terminal 'O' present in the compound 'C' is

Given below are two statements: In the light of the above statements, choose the correct answer from the options given below

1. Statement I is true but Statement II is false
2. Both Statement I and Statement II are true
3. Both Statement I and Statement II are false
4. Statement I is false but Statement II is true

Among Sc, Mn, Co and Cu, identify the element with highest enthalpy of atomisation. The spin only magnetic moment value of that element in its +2 oxidation state is BM (in nearest integer).

The spin-only magnetic moment value of Mn+ ion formed among Ni, Zn, Mn and Cu that has the least enthalpy of atomisation is . (in nearest integer) Here n is equal to the number of diamagnetic complexes among K2[NiCl4], [Zn(H2O)6]Cl2, K3[Mn(CN)6] and [Cu(PPh3)3I]

The correct option with order of melting points of the pairs (Mn, Fe), (Tc, Ru) and (Re, Os) is :

1. Fe < Mn, Ru < Tc and Re < Os
2. Fe < Mn, Ru < Tc and Os < Re
3. Mn < Fe, Tc < Ru and Re < Os
4. Mn < Fe, Tc < Ru and Os < Re

The molar mass of the water insoluble product formed from the fusion of chromite ore (FeCr2O4) with Na2CO3 in presence of O2 is g mol-1.

Consider 'n' is the number of lone pair of electrons present in the equatorial position of the most stable structure of ClF3. The ions from the following with 'n' number of unpaired electrons are Choose the correct answer from the options given below:

1. B and D Only
2. A, D and E Only
3. B and C Only
4. A and C Only

Which of the following oxidation reactions are carried out by both K2Cr2O7 and KMnO4 in acidic medium? Choose the correct answer from the options given below :

1. A, B and C Only
2. C, D and E Only
3. B, C and D Only
4. A, D and E Only

The amphoteric oxide among V2O3, V2O4 and V2O5, upon reaction with alkali leads to formation of an oxide anion. The oxidation state of V in the oxide anion is :

1. + 4
2. + 5
3. + 3
4. + 7

The spin only magnetic moment ( ) value (B.M.) of the compound with the strongest oxidising power among Mn2O3, TiO and VO is B.M. (Nearest integer).