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d- and f-Block Elements · Question 1

JEE Main 2026 (Online) 8th April Evening ShiftMCQMedium📈 Topic in 32% papers+4−1
1

Given below are two statements : In the light of the above statements, choose the correct answer from the options given below :

  1. Both Statement I and Statement II are correct
  2. Both Statement I and Statement II are incorrect
  3. Statement I is correct but Statement II is incorrect
  4. Statement I is incorrect but Statement II is correct

Answer

(1) Both Statement I and Statement II are correct

Solution

Statement I: an ion is coloured when it has unpaired d electrons (d–d transition).

Ti4+: 3d0 colourless; V2+: 3d3 violet; Mn2+: 3d5 pink; Fe3+: 3d5 yellow; Cr2+: 3d4 blue

⇒ Both ions coloured in [V2+, Mn2+], [Mn2+, Fe3+] and [V2+, Cr2+] = 3 pairs ⇒ Statement I is correct.

Statement II: La3+ (4f0), Yb2+ ( 4f14), Lu3+ ( 4f14), Ce4+ (4f0), Ac3+ (5f0), Lr3+ ( 5f14)

⇒ No ion has an unpaired electron ⇒ all diamagnetic ⇒ 3 pairs ⇒ Statement II is correct.

Answer: (1)

JEE Main 2026 (Online) 8th April Evening Shift

Keep practising — d- and f-Block Elements

2

Given below are two statements for catalytic properties of transition metals. In the light of the above statements, choose the correct answer from the options given below :

  1. Both Statement I and Statement II are correct
  2. Both Statement I and Statement II are incorrect
  3. Statement I is correct but Statement II is incorrect
  4. Statement I is incorrect but Statement II is correct
JEE Main 2026 (Online) 8th April Evening Shift
3

The correct statements among the following are : Choose the correct answer from the options given below :

  1. A and B Only
  2. A, C and D Only
  3. C and D Only
  4. B, C and D Only
JEE Main 2026 (Online) 6th April Morning Shift
4

The correct order of first ( iH1) and second ( iH2) ionisation enthalpy values of Cr and Mn are : Choose the correct answer from the options given below :

  1. A and B only
  2. B and C only
  3. A and D only
  4. C and D only
JEE Main 2026 (Online) 6th April Evening Shift
5

Which of the following is NOT a physical or chemical characteristics of interstitial compounds?

  1. They have high melting points, higher than those of pure metals.
  2. They are very soft and ionic in nature.
  3. They retain metallic conductivity.
  4. They are chemically inert and usually non-stoichiometric.
JEE Main 2026 (Online) 5th April Morning Shift
6

Given below are two statements : In the light of the above statements, choose the correct answer from the options given below :

  1. Both Statement I and Statement II are correct
  2. Both Statement I and Statement II are incorrect
  3. Statement I is correct but Statement II is incorrect
  4. Statement I is incorrect but Statement II is correct
JEE Main 2026 (Online) 5th April Evening Shift
7

The correct statements among the following are, Choose the correct answer from the options given below :

  1. A and B Only
  2. C and D Only
  3. B and D Only
  4. A and C Only
JEE Main 2026 (Online) 4th April Morning Shift
8

Correct statements from the following are Choose the correct answer from the options given below :

  1. A, B and C Only
  2. A, C and D Only
  3. A and C Only
  4. B and D Only
JEE Main 2026 (Online) 4th April Morning Shift
9

Match the LIST-I with LIST-II Choose the correct answer from the options given below :

  1. A-I, B-III, C-IV, D-II
  2. A-II, B-I, C-III, D-IV
  3. A-IV, B-II, C-I, D-III
  4. A-III, B-I, C-IV, D-II
JEE Main 2026 (Online) 4th April Morning Shift
10

Pairs of elements with the same number of electrons in their respective 4f orbital are [Atomic number. Eu-63, Gd-64, Dy-66, Ho-67, Tm-69, Yb-70, Lu-71, Hf-72] Choose the correct answer from the options given below :

  1. B and C Only
  2. A and B Only
  3. A and D Only
  4. A and C Only
JEE Main 2026 (Online) 4th April Evening Shift
11

Consider |x| is the difference in oxidation states of Mn in highest manganese fluoride and highest manganese oxide. The ions with |x| number of unpaired electrons from the following are : Choose the correct answer from the options given below :

  1. A and B Only
  2. C, D and E Only
  3. C and E Only
  4. B and E Only
JEE Main 2026 (Online) 4th April Evening Shift

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