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s-Block Elements · Question 29

AIPMT 2010 (Prelims)MCQEasy📈 Topic in 12% papers+4−1
1

Which of the following alkaline earth metal sulphates has hydration enthalpy higher than the lattice enthalpy?

  1. CaSO4
  2. BeSO4
  3. BaSO4
  4. SrSO4

Answer

(2) BeSO4

Solution

Be2+ is the smallest ion of the group, its hydration enthalpy is very high.

As per NCERT, the greater hydration enthalpies of Be2+ and Mg2+ ions overcome the lattice enthalpy factor, so their sulphates are soluble in water.

Down the group hydration enthalpy decreases faster than lattice enthalpy ⇒ CaSO4, SrSO4, BaSO4 are sparingly soluble.

∴ For BeSO4, hydration enthalpy > lattice enthalpy.

Answer: (2)

Out of syllabusAIPMT 2010 (Prelims)

Keep practising — s-Block Elements

2

Property of the alkaline earth metals that increases with their atomic number

  1. solubility of their hydroxides in water
  2. solubility of their sulphates in water
  3. ionization energy
  4. electronegativity
Out of syllabusAIPMT 2010 (Prelims)
3

Which one of the following compounds is a peroxide?

  1. KO2
  2. BaO2
  3. MnO2
  4. NO2
Out of syllabusAIPMT 2010 (Prelims)
4

Which of the following oxides is not expected to react with sodium hydroxide?

  1. CaO
  2. SiO2
  3. BeO
  4. B2O3
Out of syllabusAIPMT 2009
5

The sequence of ionic mobility in aqueous solution is

  1. Rb+ > K+ > Cs+ > Na+
  2. Na+ > K+ > Rb+ > Cs+
  3. K+ > Na+ > Rb+ > Cs+
  4. Cs+ > Rb+ > K+ > Na+
Out of syllabusAIPMT 2008
6

The alkali metals form salt-like hydrides by the direct synthesis at elevated temperature. The thermal stability of these hydrides decreases in which of the following orders?

  1. NaH > LiH > KH > RbH > CsH
  2. LiH > NaH > KH > RbH > CsH
  3. CsH > RbH > KH > NaH > LiH
  4. KH > NaH > LiH > CsH > RbH
Out of syllabusAIPMT 2008
7

The correct order of increasing thermal stability of K2CO3, MgCO3, CaCO3 and BeCO3 is

  1. BeCO3 < MgCO3 < CaCO3 < K2CO3
  2. MgCO3 < BeCO3 < CaCO3 < K2CO3
  3. K2CO3 < MgCO3 < CaCO3 < BeCO3
  4. BeCO3 < MgCO3 < K2CO3 < CaCO3
Out of syllabusAIPMT 2007
8

In which of the following the hydration energy is higher than the lattice energy?

  1. MgSO4
  2. RaSO4
  3. SrSO4
  4. BaSO4
Out of syllabusAIPMT 2007
9

The correct order of the mobility of the alkali metal ions in aqueous solution is

  1. Rb+ > K+ > Na+ > Li+
  2. Li+ > Na+ > K+ > Rb+
  3. Na+ > K+ > Rb+ > Li+
  4. K+ > Rb+ > Na+ > Li+
Out of syllabusAIPMT 2006
10

A solid compound X on heating gives CO2 gas and a residue. The residue mixed with water forms Y. On passing an excess of CO2 through Y in water, a clear solution Z is obtained. On boiling Z, compound X is reformed. The compound X is

  1. Ca(HCO3)2
  2. CaCO3
  3. Na2CO3
  4. K2CO3
Out of syllabusAIPMT 2004
11

In which of the following processes, fused sodium hydroxide is electrolysed at a temperature of 330 C for extraction of sodium?

  1. Castner's process
  2. Downs process
  3. Cyanide process
  4. Both (2) and (3)
Out of syllabusAIPMT 2002

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