Given below are two statements: In the light of the above statements, choose the correct answer from the options given below :
- Statement I is false but statement II is true
- Both statement I and statement II are true
- Both statement I and statement II are false
- Statement I is true but statement II is false
Answer
(2) Both statement I and statement II are true
Solution
Statement I: trihalides MX3 of group 13 are largely covalent ⇒ easily hydrolysed by water, e.g. BCl3 + 3H2O B(OH)3 + 3HCl ⇒ true
Statement II: Al can use its vacant 3d orbitals (CN = 6):
AlCl3 + 6H2O [Al(H2O)6]3+ + 3Cl- (sp3d2, octahedral) ⇒ true
Answer: (2)