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Electrochemistry

JEE Main 2024 (Online) 1st February Morning ShiftNumericalEasy📈 Topic in 29% papers+4
Ques. 1JEE Main 2024, 1 February (Morning Shift)

The potential for the given half cell at 298 K is (-) 10-2 V 2H+(aq) + 2e- H2(g) [H+] = 1 M, PH2 = 2 atm (Given : 2.303 RT/F = 0.06 V, 2 = 0.3)

Answer

1

Solution

Nernst equation (n = 2), E H+/H2 = 0:

E = E - 0.062 PH2[H+]2

⇒ E = 0 - 0.03 212

⇒ E = -0.03 0.3 = -0.009 V

∴ E = -0.9 10-2 V ≈ -1 10-2 V (nearest integer)

Answer: 1

Keep practising — Electrochemistry

Ques. 2JEE Main 2024, 1 February (Evening Shift)

The amount of electricity in Coulomb required for the oxidation of 1 mol of H2O to O2 is 105 C.

Ques. 3JEE Main 2024, 1 February (Evening Shift)

Consider the following redox reaction : MnO4- + H+ + H2C2O4 Mn2+ + H2O + CO2 The standard reduction potentials are given as below ( E0red ) : E MnO4-/Mn2+ = +1.51 V E CO2/H2C2O4 = -0.49 V If the equilibrium constant of the above reaction is given as Keq = 10x, then the value of x = (nearest integer)

Ques. 4JEE Main 2024, 31 January (Morning Shift)

Identify the factor from the following that does not affect electrolytic conductance of a solution.

  1. The nature of solvent used.
  2. The nature of the electrolyte added.
  3. The nature of the electrode used.
  4. Concentration of the electrolyte.
Ques. 5JEE Main 2024, 31 January (Morning Shift)

One Faraday of electricity liberates x 10-1 gram atom of copper from copper sulphate. x is .

Ques. 6JEE Main 2024, 31 January (Evening Shift)

The values of conductivity of some materials at 298.15 K in S m-1 are 2.1 103, 1.0 10-16, 1.2 10, 3.91, 1.5 10-2, 1 10-7, 1.0 103. The number of conductors among the materials is .

Ques. 7JEE Main 2024, 30 January (Evening Shift)

Reduction potential of ions are given below: [figure] The correct order of their oxidising power is :

  1. IO4- > BrO4- > ClO4-
  2. BrO4- > ClO4- > IO4-
  3. ClO4- > IO4- > BrO4-
  4. BrO4- > IO4- > ClO4-
Ques. 8JEE Main 2024, 29 January (Morning Shift)

The mass of zinc produced by the electrolysis of zinc sulphate solution with a steady current of 0.015 A for 15 minutes is 10-4 g. (Atomic mass of zinc = 65.4 amu)

Ques. 9JEE Main 2024, 29 January (Evening Shift)

A constant current was passed through a solution of AuCl4- ion between gold electrodes. After a period of 10.0 minutes, the increase in mass of cathode was 1.314 g. The total charge passed through the solution is 10-2 F. (Given atomic mass of Au = 197)

Ques. 10JEE Main 2024, 27 January (Morning Shift)

The mass of silver (Molar mass of Ag : 108 g mol-1) displaced by a quantity of electricity which displaces 5600 mL of O2 at S.T.P. will be g.

Ques. 11JEE Main 2024, 27 January (Evening Shift)

Which of the following statements is not correct about rusting of iron?

  1. Rusting of iron is envisaged as setting up of electrochemical cell on the surface of iron object.
  2. Dissolved acidic oxides SO2, NO2 in water act as catalyst in the process of rusting.
  3. Coating of iron surface by tin prevents rusting, even if the tin coating is peeling off.
  4. When pH lies above 9 or 10, rusting of iron does not take place.

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