The structures of beryllium chloride in solid state and vapour phase, are :
- Chain in both
- Chain and dimer, respectively
- Linear in both
- Dimer and Linear, respectively
Answer
(2) Chain and dimer, respectively
Solution
As per NCERT, beryllium chloride has a chain structure in the solid state (each Be bridged to its neighbours through two Cl atoms).
In the vapour phase BeCl2 tends to form a chloro-bridged dimer, which dissociates into the linear monomer at high temperatures of the order of 1200 K.
Solid: chain; vapour: dimer.
Answer: (2)